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  • Chemistry  (45)
  • Electron microscopy  (4)
  • Monocytes  (4)
  • Nederland
  • Magnetism
  • 1975-1979  (52)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Cell & tissue research 188 (1978), S. 361-373 
    ISSN: 1432-0878
    Keywords: Macrophages ; Monocytes ; Peroxidatic activity ; Mouse
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary A description is given of the distribution of peroxidatic (PO) activity in murine monocytes of blood and peritoneal cavity, and in murine macrophages residing in the unstimulated peritoneal cavity as well as in liver, spleen, bone marrow, and small intestine. In the monocytes, PO activity is restricted to some of the cytoplasmic granules; in the tissue (or resident) macrophages present in peritoneal cavity, liver, spleen, and small intestine, the PO activity is located in the nuclear envelope and the rough endoplasmic reticulum. Macrophages in the bone marrow are PO-negative. In the spleen and bone marrow, reticulum cells show PO activity in the nuclear envelope and the RER. Transitional forms between monocytes and tissue macrophages were not observed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 16 (1977), S. 1735-1745 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Infrared spectroscopy was used for the determination of the base-pairing content of four specific tRNAs in deuterium oxide solution. Infrared spectra were obtained in the 1750-1550 cm-1 region at various temperatures ranging from about 15 to 90°C. Melting curves were constructed by plotting the molar extinction coefficient at ν = 1657 cm-1 versus temperature. These transition curves enabled us to determine the ranges of temperature which correspond to the ordered (partially double-stranded) or randomly coiled structure of the tRNA. For a set of wavenumbers the extinction coefficients at these temperatures were used for the calculation of the base-pairing content. The procedure employed here is based on a method described earlier by Thomas [(1969) Biopolymers 7, 325-334]. For the conditions selected for this investigation (Mg2+-free D2O-buffer; 0.01M tris-DCl, 0.015M NaCl, pD 7.5) the results of this determination agree within the limits of errors with the number of base pairs predicted by the cloverleaf model.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Organic radicals were produced in the tensides C16H33(OCH2CH2)21OH and C14H29(OCH2CH2)3-SO3Na in aqueous solutions using a short pulse of high energy electrons. The radicals were formed by OH attack on the (OCH2CH2)x-parts of the tensides. The decay of the 250nm absorption of the radicals was recorded at different initial radical concentrations and tenside concentrations. Several radicals could be produced in one micelle. Radicals formed in the same micelle decay within microseconds or faster. The half life time τ1 in a micelle carrying two radicals is 2,0·10-6 s for C16H33(OCH2CH2)21 OH and less than 6·10-7 s for C14H29(OCH2CH2)3SO3Na. A model for intramicellar radical-radical reactions is proposed according to which the rate is faster in tensides of high critical micelle concentration. Single radicals in micelles of C16H33(OCH2CH2)21OH can deactivate each other without leaving the micelles. This intermicellar reaction is discussed in terms of the rate of diffusion-controlled micelle-micelle encounters, an encounter time of 7·10-8s, and the above time τ1 for intramicellar reaction. The observed rate constant 2k of intermicellar reaction is 3,5·106 mol-1·l·s-1. At low tenside concentrations, the bimolecular rate constant increases since more single tenside radicals are present in solution. They react rapidly (ca. 108 mol-1·l·s-1) with radicals in micelles. Single radicals in C14H33(OCH2CH2)3-SO3Na micelles cannot directly react with each other because of the Coulombic repulsion between two anionic micelles. Reaction occurs after the exit of a tenside radical from its micelle, the rate of which depends on the micellar equilibrium Mn⇄Mn-1+M (M: tenside molecule; n: agglomeration number of micelle). A single radical in solution reacts with a single radical in a micelle with 2k = 1,0·108 mol-1·l·s-1 and with another single radical in solution with 4,0·107 mol-1·l·s-1.γ-Irradiation of both tensides in aqueous solution leads to slight increases in viscosity, followed by turbidity beyond the “gel dose” and phase separation. These effects are explained in terms of crosslinking of tenside molecules. Formation of a large network requires bridges between all participating tenside molecules (not only bridges between micelles).
    Additional Material: 11 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 1 (1978), S. 97-97 
    ISSN: 0935-6304
    Keywords: Liquid Chromatography ; Structure and relation of polyhalogenated aromatics ; discussed ; Silica gel/aluminium oxide compared ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, glass ; Separation of polychloro biphenyls ; Separation of organochlorine pesticides ; Splitless automated injection ; Residue level ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Complicated PCB mixtures can be separated in individual compounds using glass capillary gas chromatography, (GC)2. Depending on extraction and clean-up procedure it is also possible to separate and determine organochlorine pesticides at the same time.This (GC)2 technique can be used to determine the contents of individual chlorinated biphenyls in milk products and animal feedstuffs and in the analysis of complicated extracts of soil and vegetable material.Practical aspects concerning connection of the capillary, automatic splitless injection, repeatability of the retention time, quality of the column with respect to separation and adsorption and degradation of DDT are discussed.The detection of individual chlorinated biphenyls is possible at the ppb level in fats and vegetable materials, using an extraction and clean-up procedure, based on saponification of the sample.Preliminary results for milk, obtained from several areas, are shown.
    Additional Material: 6 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 406-413 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Form and Mechanisms of Cracks and Fractures Caused by Simultaneous Corrosive and Dynamic Stress under Various FrequenciesDistinction of crack nucleation and crack propagation under variable frequencies and electrolytic corrosion. Relationship between crack nucleation and frequency due to differing sliding mechanisms. Crack propagation under decreasing frequencies causes transition from corrosion fatigue to cyclic stress corrosion cracking and finally stress corrosion cracking can be observed. Coordination of that transition with the increasing influence of the KISCC-value as determinant of the crack propagation.The influence of frequency on high temperature materals in hot gas atmosphere is mainly determined by creep mechanisms during top-load phase and the gas-metal-reactions. Accordingly the life time increases with growing load frequency.
    Notes: Anrißphase und Phase des Rißfortschritts bei der Betrachtung der Frequenzabhängigkeit unter elektrolytischer Korrosion. Abhängigkeit der Anrißphase von der Frequenz infolge unterschiedlicher Gleitmechanismen. Beim Rißfortschritt erfolgt mit sinkender Frequenz Übergang von Schwingungsrißkorrosion zu zyklischer Spannungsrißkorrosion und schließlich zu Spannungsrißkorrosion. Zuordnung dieses Übergangs zum zunehmenden Einfluß des KISCC-Wertes als Bestimmungsgröße für den Bruchvorgang.Frequenzabhängigkeit bei Hochtemperaturwerkstoffen in Heißgasatmosphäre im wesentlichen bestimmt durch Kriechvorgänge bei Einwirkung der Oberlast und zeitabhängige Gas-Metall-Reaktionen. Entsprechend verlängern sich die Standzeiten mit zunehmender Belastungsfrequenz.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 2 (1979), S. 11-14 
    ISSN: 0935-6304
    Keywords: Liquid chromatography ; Fluorescence ; Ion-pair extraction ; Amines ; Post-column reaction ; Auto-analyser ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A detection system is described which is based on fluorescent ion-pair formation between tertiary amine drugs and dimethoxyanthracene sulphonate. A dynamic micro-extraction principle is then used to isolate the ion-pairs from the excess reagent. The band broadening of this extraction detector was kept below 20% using standard auto-analyser equipment. With the enhanced selectivity and sensitivity of this approach it was possible to analyse chloropheniramine in urine at ppb concentrations using a pre-column clean-up trace enrichment step.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 2 (1979), S. 79-81 
    ISSN: 0935-6304
    Keywords: Thin Layer Chromatography TLC ; Chemically bonded C8 on precoated HPTLC plates tested 6 dialcylphthalates used as test substances ; 15-20% (v/v) water in organic solvents, upper practical limit as mobile phase composition ; 11-50 min migration time for linear TLC, 50 mm height ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 30 (1979), S. 89-89 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Cell & tissue research 203 (1979), S. 209-221 
    ISSN: 1432-0878
    Keywords: Erythrophagocytosis ; Lysosomes ; Placenta (sheep) ; Acid phosphatase ; Electron microscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary In trophoblastic epithelial cells of the sheep placenta the breakdown of erythrocytes within complex erythrolysosomes was studied at the ultrastructural level. It was found that the formation of complex erythrolysosomes containing from two to several erythrocytes as a result of fusion of erythrolysosomes within the epithelial cells was a common occurrence when the epithelial cells engulfed a large number of erythrocytes. The erythrocytes enclosed in complex erythrolysosomes appear to be either in the same or in different stages of hemolysis. In the process of breakdown of erythrocytes within complex erythrolysosomes five successive stages of hemolysis could be distinguished. Acid phosphatase activity was demonstrated in the complex erythrolysosomes and appeared to be located in the angular interspaces between the erythrocytes and the lysosomal membrane. The fragmentation of complex erythrolysosomes with formation of small hemoglobin-containing lysosomes also occurred. The fusion of erythrolysosomes with formation of complex erythrolysosomes can be considered as an additional mechanism in the process of erythrocyte breakdown in the epithelial cells of the sheep placenta.
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