Electronic Resource
Springer
Il nuovo cimento della Società Italiana di Fisica
16 (1994), S. 1601-1611
ISSN:
0392-6737
Keywords:
Electron correlation calculations for atoms and molecules
;
Conference proceedings
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Summary The structure of water in water/AOT/n-heptane reverse micelles has been studied as a function of the [H2O]/[AOT] ratio (W) by using the absorption IR due to O−H stretching modes in the 3800–3000 cm−1 range. The results show that the IR spectra can be expressed as a sum of contributions from bound- and bulk-like water. The fraction of water in the two «regions» within the water pool was evaluated as a function ofW. The «bound» water region seems to hold 3.5 water molecules (corresponding to 7 O−H oscillators) per AOT molecule and its formation is nearly complete atW〉6.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02462048
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