ISSN:
0009-2940
Keywords:
Charge-transfer complexes
;
Electric conductivity
;
Segregated stacking
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Conducting Charge-Transfer Complexes of 2,5-Bis(cyanoimino)-2,5-dihydrothieno[3,2-b]thiophenes with Organic DonorsFrom the title compound 4 and several donors 13 charge-transfer (CT) complexes have been obtained. Most of them show powder conductivities of 0.01-2.0 Scm-1. The crystal structure of 4d/TTF (20 Scm-1) reveals segregated stacks of donor and acceptor molecules in a novel stacking pattern. The structure of 4d/TMTSF consists of mixed stacks (insulator), however a second phase (no structure available) exhibits very high conductivity (200 Scm-1).
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250820
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