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  • Analytical Chemistry and Spectroscopy  (9)
  • Elastic scattering of atoms and molecules  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 2 (1983), S. 1347-1375 
    ISSN: 0392-6737
    Keywords: Elastic scattering of atoms and molecules ; Inelastic scattering of atoms and molecules
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Description / Table of Contents: Riassunto Si dà un resoconto particolareggiato di un calcolo perturbativo della sezione d'urto elastica e di eccitazione vibrazionale per la collisione positronio su molecola d'idrogeno. Il problema è studiato nel contesto della teoria dello scattering a molti canali per sistemi di particelle identiche; sono calcolate l'ampiezza di scambio al primo ordine e l'ampiezza diretta al secondo ordine per energie da zero alla soglia di eccitazione del positronio. È anche valutata l'approssimante di Padé piú bassa e questo suggerisce la comparsa di una forte esaltazione della sezione d'urto vibrazionale e della perdita di energia nella materia attorno alla soglia di eccitazione del positronio. Rispetto ad un breve resoconto preliminare presentato in precedenza si sono apportati diversi miglioramenti sia nelle approssimazioni di carattere fisico che nelle valutazioni numeriche.
    Abstract: Резюме Проводится пертурбационное вычисление поперечных сечений упругого рассеяния и вибрационного возбуждения в процессе рассеяния позитрония на молекуле H2. Рассматриваемая проблема исследуется в связи с теорией многоканального рассеяния тождественных частиц. Вычисляются обменная амплитуда первого порядка и прямая амплитуда второго порядка в области энергий от нуля до порога возбуждения позитрония. Также определяется низший порядка Падэ приближения, предполагая наличие сильного увеличения в вибрационном поперечном сечении и в энергетических потерях в веществе на пороге возбуждения позитрония. По сравнению с существующими подходами, предлагаются различные улучшения в физических приблизениях и в численных расчетах.
    Notes: Summary A detailed account is reported of a perturbative calculation of the elastic and vibrational excitation cross-sections for the positronium-H2 molecule scattering. The problem is studied in the context of the multichannel scattering theory for identical particles; the first-order exchange amplitude and the second-order direct amplitude are evaluated for energy from zero to the positronium excitation threshold. The lowest-order Padé approximant is also constructed and this suggests the occurrence of a strong enhancement in the vibrational cross-section and in the related energy loss in matter at the positronium excitation threshold. In comparison with a short preliminary account presented elsewhere, various improvements are introduced both in the physical approximations and in the numerical calculations.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 6 (1985), S. 105-123 
    ISSN: 0392-6737
    Keywords: Elastic scattering of atoms and molecules ; Inelastic scattering of atoms and molecules
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Description / Table of Contents: Riassunto Si presenta un calcolo perturbativo della sezione d'urto elastica, di prima e seconda eccitazione vibrazionale per la collisione di positronio su molecola d'idrogeno per energie da zero alla soglia di prima eccitazione del positronio. Si calcola il rapporto tra la perdita di energia vibrazionale ed elastica del positronio nella materia. Rispetto ad un analogo calcolo fatto precedentemente si tiene conto del contributo del continuo del positronio all'ampiezza diretta al second'ordine e si valuta la sezione d'urto di seconda eccitazione vibrazionale.
    Abstract: Резюме В рамках теории возмущений вычисляются поперечное сечение упругого рассеяния и поперечное сечение первого и второго колебательных возбуждений при соударении позитрония с молекулой водорода при энергиях в диапазоне от нуля до порога возбуждения позитрония. Мы также вычисляем отношение между потерями энергии на колебательные возбуждения и упругими потерями энергии позитрония в веществе. По сравнению с предыдущими вычислениями мы учитываем вклад непрерывного спектра позитрония в прямую амплитуду во втором борновском приближении. Мы также оцениваем поперечное сечение второго колебательного возбуждения.
    Notes: Summary We perform a perturbative calculation of the elastic, first and second vibrational excitation cross-sections for the positronium-H2 molecule scattering for an energy from zero to the positronium excitation threshold. We calculate also the ratio between the averaged vibration threshold. We calculate also the ratio between the averaged vibrational-and elastic-energy loss of the positronium in matter. In comparison with a previous similar calculation, we take now into account the contribution of the continuum of the positronium to the second Born approximation to the direct amplitude and we add the calculation of the second vibrational excitation cross-section.
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  • 3
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Fast-atom bombardment (FAB) mass spectrometry linked with collision spectroscopy has been employed for the structural characterization of eight underivatized 1,4-benzodiazepines. Both positive- and negative-ion FAB led, in all cases examined, to the production of abundant molecular species. Collision experiments performed on such ions gave rise to the identification of diagnostic fragment ions, that could be related to the original structure.
    Additional Material: 2 Ill.
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  • 4
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of several imidazo[l,5-a]benzodiazepin-6-one derivatives of neuropharmacological significance were determined in order to establish their decomposition paths under electron impact. A novel distonic fragment ion was observed and it was possible to demonstrate by consideration of metastable ions and by tandem mass spectrometry that it undergoes isomerization to the corresponding classical structure.
    Additional Material: 7 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 26 (1991), S. 961-966 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The positive-ion fast atom bombardment (FAB) mass spectra of eserine and some carbamate analogues were recorded and showed a partially different fragmentation process, with respect to that of the corresponding chemical ionization (Cl) fragmentation. This unexpected behaviour could be explained by taking into account the known solution chemical behaviour of the protonated species, and assigning to the molecular species observed under FAB a different-yet related-molecular connectivity. This may be considered as evidence that the sputtered species under FAB closely reflect the chemical behaviour of the analysed molecule in the solution environment.
    Additional Material: 3 Ill.
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  • 6
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Low-energy collision-induced dissociation of some representative 3-picolinyl esters of fatty acids were investigated. The daughter-ion spectra of the precursor ions showed similar features to the electron impact mass spectra, but the low intensity of the parent-ion signal did not allow reliable deductions. The parent-ion spectra of some fragments that retain the pyridine derivatizing group contain structurally useful information, and are suitable for analytical application. These spectra also contain fragment ions which may account for an alternative pathway to that currently proposed for the generation of certain fragment ions within the ion source. Both pathways were investigated in this tandem mass spectrometric study. Isomerization and decomposition of distonic fragment ions through loss of alkenes yield species with a shorter alkyl chain, which are particularly stable when they contain allylic radicals.
    Additional Material: 8 Ill.
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  • 7
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fragmentation of protonated and cationized sphingosine and sphinganine under metastable and high-energy collision-induced decomposition is reported. The protonated compounds undergo abundant charge-remote fragmen tation of the long alkyl chain, while the cationized molecules yield much less abundant fragmentation and little or no electrocyclic fission of the hydrocarbon portion.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 1000-1004 
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The neuroleptic butyrophenone drug spiroperidol (8-[4-fluorophenyl)-(4-oxobutyl]-1-phenyl-1,3,8-triazaspiro[4,5]decan-4-one) and related compounds are valuable tools for mapping the dopamine receptors in the brain. During the development of the radiochemical synthesis of these compounds with very short-lived isotopes suitable for positron emission tomography studies, positive electron impact mass spectrometric information was obtained. Ion series are present in the spectra of all 12 compounds studied, which unambiguously allow recognition of type and site of substitution on the spiro system.
    Additional Material: 2 Tab.
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  • 9
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The characterization of the N-blocked neuropeptide N-acetyl-aspartyl-glutamic acid and of some related compounds was carried out by negative-ion fast atom bombardment mass spectrometry and collision-induced dissociation of the generated [M - H]- species. Thorough analysis of the fragment ion spectra allowed discrimination between sequence isomeric compounds, and highlighting of differences between dipeptides linked in the normal or iso mode.
    Additional Material: 2 Ill.
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  • 10
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A mass spectrometric investigation on the anti-inflammatory drug o-(2,6-dichlorophenyl)aminophenylacetic acid (Diclofenac) and its hydroxylated metabolites is performed by means of electron impact, chemical ionization and fast atom bombardment. Tandem mass spectrometry of isomeric monohydroxylated compounds allows assessment of the substitution pattern on the two aryl rings.
    Additional Material: 2 Ill.
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