ALBERT

Description: The linear polarization of sunlight reflected by ocean surfaces in the shortwave infrared (SWIR), at geometries where specular reflection dominates the signal, is a direct function of the refractive index of the surface microlayer(SML). This simple physical concept is at the base of a novel technique presented in this study. We invert observations obtained by the airborne Research Scanning Polarimeter (RSP) in the sun glint region, where each pixel's radiance is dominated by the signal originating from the wave slopes oriented precisely to cause specular reflection. The SWIR wavelength ensures minimization of aerosol interference when radiance travels through the atmosphere; strong absorption by the water body then limits the penetration depth to the first micrometer or so, effectively probing the SML. The resulting Degree of Linear Polarization (DoLP) is then governed by the refractive index via the Fresnel law for the specfic pixel geometry, independently of the wind speed. The selected dataset concerns several field deployments from both low- and high-altitude aircraft, including total reflectance measurements with the sole purpose of accounting for the residual aerosol effect.Stable retrievals from transects above pure seawater yielded values of refractive index that match the values published in the literature within an accuracy of 5 x 10 [superscript 4]. Flying over the oil spill caused by the explosion of the Deepwater Horizon platform, detected variations were found compatible with the presence of an oil slick. The robustness of the results, guaranteedby the high RSP polarimetric accuracy (less than or equal to 0:2%), opens the possibility for remote-sensing detection of other entities that similarly affect the refractive index including whitecaps, microplastics, biological gels, seaweed and grass mats.

Description: Remote sensing has mainly relied on measurements of scalar radiance and its spectral and angular features to retrieve micro- and macro-physical properties of aerosols/hydrosols. However, it is recognized that measurements that include the polarimetric characteristics of light provide more intrinsic information about particulate scattering. To take advantage of this, we used vector radiative transfer (VRT) simulations and developed an analytical relationship to retrieve the macro and micro-physical properties of the oceanic hydrosols. Specifically, we investigated the relationship between the observed degree of linear polarization (DoLP) and the ratio of attenuation-to- absorption coefficients (c/a) in water, from which the scattering coefficient can be readily computed (b equals c minus a), after retrieving a. This relationship was parameterized for various scattering geometries, including sensor zenith/azimuth angles relative to the Sun's principal plane, and for varying Sun zenith angles. An inversion method was also developed for the retrieval of the microphysical properties of hydrosols, such as the bulk refractive index and the particle size distribution. The DoLP vs c/a relationship was tested and validated against in-situ measurements of underwater light polarization obtained by a custom-built polarimeter and measurements of the coefficients a and c, obtained using an in-water WET (Western Environmental Technologies) Labs ac-s (attenuation coefficients In-Situ Spectrophotometer) instrument package. These measurements confirmed the validity of the approach, with retrievals of attenuation coefficients showing a high coefficient of determination depending on the wavelength. We also performed a sensitivity analysis of the DoLP at the Top of Atmosphere (TOA) over coastal waters showing the possibility of polarimetric remote sensing application for ocean color.