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ESR spectra of γ-irradiated samples of iron(iii) binuclear complexes (1996)

Kuzina, S. I. ; Mikhailov, A. I. ; Nesterenko, G. N. ; [et al.]

Springer

Russian chemical bulletin 45 (1996), S. 824-826

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ISSN: 1573-9171

Keywords: binuclear iron(iii) complexes ; γ-irradiation ; ESR

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract γ-Irradiation of μ-oxo-bridged binuclear iron complexes FeIII 2OL n in a glycerol or dimethylformamide matrix at 77 K affords unstable mixed-valence FeIIFIII forms resulting from the transfer of a mobile electron generated by the ionizing radiation. These nonequilibrium forms retain the ligand environment of the original complexes, and their ESR spectra at 77–200 K are characterized by an asymmetric signal with an axially anisotropicg-factor, which is in agreement with the spectra of the FeIIFe syu forms obtained by chemical reduction.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01431305

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