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  • 1
    Publication Date: 2013-08-31
    Description: Results form modeling studies of the Antarctic lower stratosphere which have attempted to simulate the large springtime ozone losses and corresponding changes in other trace constituents are given. These studies were carried out in a photochemical box model, a one-dimensional model without transport and in a two-dimensional photochemical-dynamical-radiation model. The photochemical studies have investigated inter alia the sensitivity of ozone to inclusion in the model of heterogeneous chemistry, and to the inclusion of the ClO dimer. When both of these are incorporated in the model, ozone depletions resembling whose found in Halley Bay in 1987 (J.C. Farman, Nature, 329, 1987) can be reproduced. The temporal variations (both diurnal and during the August to October period) of a number of important tracers including HCl, ClONO2, OClO and BrO are discussed. The two-dimensional study concentrated on the difficulty of establishing in the model the dynamical preconditioning of the lower polar stratosphere - low temperatures, low N2O, etc., high ClOx. Calculations are presented to show: (1) the depletion of ozone during the springtime season, (2) the effect of large ozone losses on lower latitudes, and (3) the longer term (multi-year) variations of ozone in Antarctica, assuming realistic increases in the atmospheric halogen burden.
    Keywords: ENVIRONMENT POLLUTION
    Type: NASA, Goddard Space Flight Center, Polar Ozone Workshop. Abstracts; p 266
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  • 2
    Publication Date: 2013-08-31
    Description: The major chemical effluents of either solid- or liquid-fueled rockets that can potentially perturb stratospheric ozone include chlorine compounds (HCl), nitrogen compounds (NO(x)), and hydrogen compounds (H2 and H2O). Radicals (Cl, ClO, H, OH, HO2, NO, and NO2) formed directly or indirectly from rocket exhaust can cause the catalytic destruction of ozone. Other exhaust compounds that could presumably lead to ozone destruction either by direct reaction with ozone or by providing a surface for heterogeneous processes include the particulates Al2O3, ice, and soot. These topics are discussed in terms of the possible effects of rocket exhausts on stratospheric ozone.
    Keywords: ENVIRONMENT POLLUTION
    Type: NASA, Washington, Scientific Assessment of Ozone Depletion: 1991; 13 p
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  • 3
    Publication Date: 2013-08-31
    Description: The largest amplitudes of the observed Quasi Biennial Oscillation (QBO) in column ozone are found in high latitudes and this must be taken into account in any explanation of the increased depletion of ozone in the southern polar spring during the 1980's. A QBO in zonal wind, temperature and column ozone has been successfully modelled in a two-dimensional dynamical/chemical model by the introduction of a parameterization scheme to model the transfer of momentum to the zonal flow associated with the damping of vertically propagating Kelvin and Rossby-Gravity waves. The largest anomalies in column ozone of approximately 20 DU are present at high latitudes. The equatorial ozone QBO is out of phase with the mid- and high-latitude ozone QBO, in good agreement with observations.
    Keywords: ENVIRONMENT POLLUTION
    Type: NASA, Goddard Space Flight Center, Polar Ozone Workshop. Abstracts; p 240-243
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  • 4
    Publication Date: 2013-08-31
    Description: The recognition of the roles of chlorine and bromine compounds in ozone depletion has led to the regulation or their source gases. Some source gases are expected to be more damaging to the ozone layer than others, so that scientific guidance regarding their relative impacts is needed for regulatory purposes. Parameters used for this purpose include the steady-state and time-dependent chlorine loading potential (CLP) and the ozone depletion potential (ODP). Chlorine loading potentials depend upon the estimated value and accuracy of atmospheric lifetimes and are subject to significant (approximately 20-50 percent) uncertainties for many gases. Ozone depletion potentials depend on the same factors, as well as the evaluation of the release of reactive chlorine and bromine from each source gas and corresponding ozone destruction within the stratosphere.
    Keywords: ENVIRONMENT POLLUTION
    Type: NASA, Washington, Scientific Assessment of Ozone Depletion: 1991; 20 p
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  • 5
    Publication Date: 2014-09-23
    Description: Our first intercomparison/assessment of the effects of a proposed high-speed civil transport (HSCT) fleet on the stratosphere is presented. These model calculations should be considered more as sensitivity studies, primarily designed to serve the following purposes: (1) to allow for intercomparison of model predictions; (2) to focus on the range of fleet operations and engine specifications giving minimal environmental impact; and (3) to provide the basis for future assessment studies. The basic scenarios were chosen to be as realistic as possible, using the information available on anticipated developments in technology. They are not to be interpreted as a commitment or goal for environmental acceptability.
    Keywords: ENVIRONMENT POLLUTION
    Type: NASA, Washington, The Atmospheric Effects of Stratospheric Aircraft: A First Program Report; p 115-157
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  • 6
    Publication Date: 2019-08-27
    Description: The main objective of the theoretical studies presented here is to apply models of stratospheric chemistry and transport in order to understand the processes that control stratospheric ozone and that are responsible for the observed variations. The model calculations are intended to simulate the observed behavior of atmospheric ozone over the past three decades (1955-1985), for which there exists a substantial record of both ground-based and, more recently, satellite measurements. Ozone concentrations in the atmosphere vary on different time scales and for several different causes. The models described here were designed to simulate the effect on ozone of changes in the concentration of such trace gases as CFC, CH4, N2O, and CO2. Changes from year to year in ultraviolet radiation associated with the solar cycle are also included in the models. A third source of variability explicitly considered is the sporadic introduction of large amounts of NO sub x into the stratosphere during atmospheric nuclear tests.
    Keywords: ENVIRONMENT POLLUTION
    Type: Report of the International Ozone Trends Panel 1988, Volume 2; p 499-542
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