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  • 1
    Electronic Resource
    Electronic Resource
    Separation of liquid mixtures by using polymer membranes, V. Water-alcohol separation by pervaporation through poly(vinyl alcohol)-graft-poly(styrene-co-maleic anhydride) membranes (1994)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 219 (1994), S. 169-184 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Ein Styrol/Maleinsäureanhydrid-Copolymeres (ST-co-MA), hergestellt aus Styrol und Maleinsäureanhydrid in Dimethylsulfoxid mit Azoisobutyronitril als Initiator, wurde durch eine Kondensationsreaktion auf Poly(vinylalkohol) (PVA) gepfropft. Die Strukturen der Produkte wurden mittels IR-Spektroskopie untersucht. Die Abhängigkeit der Pfropfterpolymerzusammensetzung, -viskosität und -ausbeute von der Konzentration der Reaktanden sowie die mechanischen Eigenschen von aus den Pfropfprodukten hergestellten Membranen wurden ermittelt. Bei der Untersuchung der Permeationseigenschaften zeigte sich, daß die Membranen bei allen Zusammensetzungen von Alkohol/Wasser-Gemischen bevorzugt für Wasser durchlässig sind. Mit steigendem PVA-Anteil in den Membranen und wachsendem Ethanolanteil der Alkohol/Wasser-Mischung nimmt die Durchlässigkeit ab und die Selektivität zu. Weiterhin wird der Einfluß der Größe der permeierenden Moleküle auf die Durchlässigkeit und Trenneigenschaften diskutiert.
    Notes: Graft copolymerization of styrene-maleic anhydride copolymer (ST-co-MA) onto poly(vinyl alcohol) (PVA) was carried out by a condensation-coupling reaction through esterification. The ST-co-MA copolymer was obtained by the copolymerization of MA and ST in dimethyl sulfoxide (DMSO), using azoisobutyronitrile as initiator. The structure of the reaction products was confirmed by infrared analysis. The dependence of composition, viscosity and yield of the graft terpolymers on the concentration of the reactants are presented in detail. Mechanical properties of membranes with different compositions were measured over a wide range of composition. It was found that water was permeated through the membranes preferentially in all ranges of feed compositions. The permeation decreased and the selectivity increased with increasing ethanol concentration in the feed and with increasing PVA content in the membrane. The effect of the molecular size of the permeating species on both permeation and separation is also discussed.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1994.052190114
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    Paper (German National Licenses)
    Fulltext
  • 2
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    Computation of the Streamfunction and Velocity Potential for Limited and Irregular Domains (2005)
    In:  Other Sources
    Details
    Publication Date: 2018-06-11
    Description: An algorithm is proposed for the computation of streamfunction and velocity potential from given horizontal velocity vectors based on solving a minimization problem. To guarantee the uniqueness of the solution and computational reliability of the algorithm, a Tikhonov regularization is applied. The solution implies that the obtained streamfunction and velocity potential have minimal magnitude, while the given velocity vectors can be accurately reconstructed from the computed streamfunction and velocity potential. Because the formulation of the minimization problem allows for circumventing the explicit specification of separate boundary conditions on the streamfunction and velocity potential, the algorithm is easily applicable to irregular domains. By using an advanced minimization algorithm with the use of adjoint techniques, the method is computationally efficient and suitable for problems with large dimensions. An example is presented for coastal oceans to illustrate the practical application of the algorithm.
    Keywords: Meteorology and Climatology
    Type: Monthly Weather Review; Volume 134; Issue 11; 3384-3394
    Format: text
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    NASA TECHNICAL REPORTS
  • 3
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    Evaluation of the Utility of the Global Seal Level Observation by TOPEX/Poseidon for Estimating the Ocean Circulation (1995)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Keywords: Meteorology and Climatology
    Type: World Meteorological Organization, Assimilation of Observations in Oceanography; Mar 13, 1995 - Mar 17, 1995; Tokyo; Japan
    Format: text
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    NASA TECHNICAL REPORTS
  • 4
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    Utilizing Ocean Thermal Energy in a Submarine Robot (2009)
    In:  CASI
    Details
    Publication Date: 2019-07-12
    Description: A proposed system would exploit the ocean thermal gradient for recharging the batteries in a battery-powered unmanned underwater vehicle [UUV (essentially, a small exploratory submarine robot)] of a type that has been deployed in large numbers in research pertaining to global warming. A UUV of this type travels between the ocean surface and depths, measuring temperature and salinity. The proposed system is related to, but not the same as, previously reported ocean thermal energy conversion (OTEC) systems that exploit the ocean thermal gradient but consist of stationary apparatuses that span large depth ranges. The system would include a turbine driven by working fluid subjected to a thermodynamic cycle. CO2 has been provisionally chosen as the working fluid because it has the requisite physical properties for use in the range of temperatures expected to be encountered in operation, is not flammable, and is much less toxic than are many other commercially available refrigerant fluids. The system would be housed in a pressurized central compartment in a UUV equipped with a double hull (see figure). The thermodynamic cycle would begin when the UUV was at maximum depth, where some of the CO2 would condense and be stored, at relatively low temperature and pressure, in the annular volume between the inner and outer hulls. The cycle would resume once the UUV had ascended to near the surface, where the ocean temperature is typically greater than or equals 20 C. At this temperature, the CO2 previously stored at depth in the annular volume between the inner and outer hulls would be pressurized to approx. equals 57 bar (5.7 MPa). The pressurized gaseous CO2 would flow through a check valve into a bladder inside the pressurized compartment, thereby storing energy of the relatively warm, pressurized CO2 for subsequent use after the next descent to maximum depth.
    Keywords: Documentation and Information Science
    Type: NPO-43304 , NASA Tech Briefs, January 2009; 19-20
    Format: application/pdf
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    NASA TECHNICAL REPORTS
  • 5
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    Alternative OTEC Scheme for a Submarine Robot (2009)
    In:  CASI
    Details
    Publication Date: 2019-07-12
    Description: A proposed system for exploiting the ocean thermal gradient to generate power would be based on the thawing-expansion/ freezing-contraction behavior of a wax or perhaps another suitable phase-change material. The power generated by this system would be used to recharge the batteries in a battery-powered unmanned underwater vehicle [UUV (essentially, a small exploratory submarine robot)] of a type that has been deployed in large numbers in research pertaining to global warming. A UUV of this type travels between the ocean surface and various depths, measuring temperature and salinity. This proposed system would be an alternative to another proposed ocean thermal energy conversion (OTEC) system that would serve the same purpose but would utilize a thermodynamic cycle in which CO2 would be the working fluid. That system is described in Utilizing Ocean Thermal Energy in a Submarine Robot (NPO-43304), immediately following this brief. The main advantage of this proposed system over the one using CO2 is that it could derive a useful amount of energy from a significantly smaller temperature difference. At one phase of its operational cycle, the system now proposed would utilize the surface ocean temperature (which lies between 15 and 20 C over most of the Earth) to melt a wax (e.g., pentadecane) that has a melting/freezing temperature of about 10 C. At the opposite phase of its operational cycle, the system would utilize the lower ocean temperature at depth (e.g., between 4 and 7 C at a depth of 300 m) to freeze the wax. The melting or freezing causes the wax to expand or contract, respectively, by about 8 volume percent.
    Keywords: Documentation and Information Science
    Type: NPO-43500 , NASA Tech Briefs, January 2009; 21-22
    Format: application/pdf
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