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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    International journal of infrared and millimeter waves 14 (1993), S. 2569-2582 
    ISSN: 1572-9559
    Schlagwort(e): Microwave ; spectra ; methanol ; CD3OH ; torsion
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The microwave spectrum of CD3OH has been studied over the 8 to 58 GHz region, and numerousb-type transitions have been assigned. Many of these belong toP subbranches which descend to the microwave region from subband origins lying much higher in the far-infrared, pass through zero frequency, and return upward again. Others are members ofb-typeQ branches which extend across the region. As well, variousa-typeK-doublet lines arising as transitions directly across the split levels of asymmetry doublets have been identified.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    International journal of infrared and millimeter waves 21 (2000), S. 1061-1083 
    ISSN: 1572-9559
    Schlagwort(e): infrared (IR) spectra ; methanol ; CD3OH ; torsion
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The Fourier transform infrared (FTIR) spectrum of the CO-stretching fundamental band of CD3OH has been recorded at a resolution of 0.002 cm-1. Assignments are reported for 35 subbands in the n = 0 ground torsional state, covering K = 0 to 9 for all torsional symmetries plus K = 10 A, and 12 assorted A and E subbands in the n = 1 first excited torsional state ranging from K = 0 up to K = 5. The subband wavenumbers have been fitted to J(J + 1) power-series energy expansions to obtain subband origins and a compact representation of the spectral observations. With the use of known ground-state energies, CO-stretch energy term values have been determined and tabulated. Least-squares fitting of the subband origins to a fourth-order Hamiltonian model for the CO-stretch mode is discussed.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2022-10-26
    Beschreibung: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Roberts, Mark L., Elder, Kathryn L., Jenkins, William J., Gagnon, Alan R., Xu, Li, Hlavenka, Joshua D., & Longworth, Brett E. C-14 Blank Corrections for 25-100 mu G samples at the National Ocean Sciences AMS Laboratory. Radiocarbon, 61(5), (2019): 1403-1411, Doi: 10.1017/RDC.2019.74.
    Beschreibung: Replicate radiocarbon (14C) measurements of organic and inorganic control samples, with known Fraction Modern values in the range Fm = 0–1.5 and mass range 6 μg–2 mg carbon, are used to determine both the mass and radiocarbon content of the blank carbon introduced during sample processing and measurement in our laboratory. These data are used to model, separately for organic and inorganic samples, the blank contribution and subsequently “blank correct” measured unknowns in the mass range 25–100 μg. Data, formulas, and an assessment of the precision and accuracy of the blank correction are presented.
    Beschreibung: This work is supported by a Cooperative Agreement (OCE-1755125) with the U.S. National Science Foundation.
    Schlagwort(e): AMS ; AMS dating ; Blank corrections
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2022-10-26
    Beschreibung: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Xu, L., Roberts, M., Elder, K., Hansman, R., Gagnon, A., & Kurz, M. Radiocarbon in dissolved organic carbon by UV oxidation: an update of procedures and blank characterization at NOSAMS. Radiocarbon, 64(1), (2022): 195-199, https://doi.org/10.1017/rdc.2022.4.
    Beschreibung: This note describes improvements of UV oxidation method that is used to measure carbon isotopes of dissolved organic carbon (DOC) at the National Ocean Sciences Accelerator Mass Spectrometry Facility (NOSAMS). The procedural blank is reduced to 2.6 ± 0.6 μg C, with Fm of 0.42 ± 0.10 and δ13C of –28.43 ± 1.19‰. The throughput is improved from one sample per day to two samples per day.
    Beschreibung: We gratefully acknowledge support from the U.S. National Science Foundation, via NSF-OCE-1755125.
    Schlagwort(e): Blank ; Dissolved organic carbon ; Radiocarbon ; UV-oxidation
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 45 (2018): 872–879, doi:10.1002/2017GL076295.
    Beschreibung: We report four profiles of the radiocarbon content of dissolved organic carbon (DOC) spanning the South Indian Ocean (SIO), ranging from the Polar Front (56°S) to the subtropics (29°S). Surface waters held mean DOC Δ14C values of −426 ± 6‰ (~4,400 14C years) at the Polar Front and DOC Δ14C values of −252 ± 22‰ (~2,000 14C years) in the subtropics. At depth, Circumpolar Deep Waters held DOC Δ14C values of −491 ± 13‰ (~5,400 years), while values in Indian Deep Water were more depleted, holding DOC Δ14C values of −503 ± 8‰ (~5,600 14C years). High-salinity North Atlantic Deep Water intruding into the deep SIO had a distinctly less depleted DOC Δ14C value of −481 ± 8‰ (~5,100 14C years). We use multiple linear regression to assess the dynamics of DOC Δ14C values in the deep Indian Ocean, finding that their distribution is characteristic of water masses in that region.
    Beschreibung: National Science Foundation (NSF) Grant Numbers: OPP-1142117, OCE-1436748
    Beschreibung: 2018-07-24
    Schlagwort(e): Radiocarbon ; Dissolved organic carbon ; Indian Ocean
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Erwartet Verfügbarkeit
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