ISSN:
0009-2940
Keywords:
Diphosphapropenes
;
CH insertion
;
Diphosphiranes
;
Chromium complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Rearrangements of the Metallodiphosphapropenes (η5-C5Me5)(CO)2FeP(SiMe3 - P = C(R)(SiMe3) (R = SiMe3, Ph)Heating of a methylcyclohexane solution of (η5-C5Me5)-(CO)2FeP(SiMe3) - P = C(SiMe3)2 (1a) gives rise to the insertion of the P = C moiety into the CH bond of a ring methyl group with formation of the chelate complex η5-ηC5Me4CH2P-[CH(SiMe3)2]P(SiMe3)Fe(CO)2 (2) which is converted into the pentacarbonylchromium derivative [5-C5Me4CH2P[CH-(SiMe3)2]P(SiMe3)[Cr(CO)5]Fe(CO)2] (3). In contrast, a similar treatment of (5-C5Me5)(CO)2FeP(SiMe3) - P = C(Ph)(SiMe3) (1 b) furnishes the diphosphirane (5-C5Me5)(CO)2FeP - C(Ph)-SiMe3) - P (SiMe3) (5). By chromatography of its (CO)5Cr adduct 6, the P - Si bond is hydrolyzed to give the (diphosphirane)-chromium complex [(5-C5Me5)(CO)2FeP-C(Ph)(SiMe3)P(H)]-Cr(CO)5 (8). The molecular structures of 3 and 8 are determined by single-crystal X-ray analysis.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260902
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