ISSN:
0749-1581
Keywords:
NMR
;
1H-NMR
;
13C-NMR
;
HMBC
;
NOESY
;
Pyridines
;
Diels-Alder reaction
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The structure of the pentasubstituted pyridines obtained in the reaction of methyl 2-isothiocyanato-3-phenylpropenoate with 1-(N,N-diethylamine)prop-1-yne were assigned based on 2D heteronuclear correlation experiments and NOE measurements. At 0°C a 2-azabicyclo[2.2.2] octa-2,7-diene intermediate was isolated and spectroscopically characterized.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260321103
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