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  • Deep Sea Drilling Project; DSDP  (4)
  • Olivine
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2009. This is the author's version of the work. It is posted here by permission of Springer for personal use, not for redistribution. The definitive version was published in Contributions to Mineralogy and Petrology 159 (2010): 689-702, doi:10.1007/s00410-009-0448-8.
    Description: The Canary Island primitive basaltic magmas 31 are thought to be derived from a HIMU-type upwelling mantle containing isotopically depleted (NMORB) component and having interacted with an enriched (EM)-type component whose origin is still a subject of debate. We have studied the relationships between Ni, Mn and Ca concentrations in olivine phenocrysts (85.6-90.0 mol.% Fo, 1722-3915 ppm Ni, 1085-1552 ppm Mn, 1222-3002 ppm Ca) from the most primitive subaerial and ODP Leg 157 high-silica (picritic to olivine basaltic) lavas with their bulk rock Sr-Nd-Pb isotope compositions (87Sr/86Sr = 0.70315- 0.70331, 143Nd/144Nd = 0.51288-0.51292, 206Pb/204Pb = 19.55-19.93, 207Pb/204Pb = 15.60- 15.63, 208Pb/204Pb = 39.31-39.69). Our data point toward the presence of both a peridotitic and a pyroxenitic component in the magma source. Using the model [Sobolev et al. (2007) The amount of recycled crust in sources of mantle-derived melts. Science 316: 412-417] in which the reaction of Si-rich melts originated during partial melting of eclogite (a high pressure product of subducted oceanic crust) with ambient peridotitic mantle forms olivine-free reaction pyroxenite, we obtain an endmember composition for peridotite with 87Sr/86Sr = 0.70337, 143Nd/144Nd = 0.51291, 206Pb/204Pb = 19.36, 207Pb/204Pb = 15.61, 208Pb/204Pb = 39.07 (EM-type endmember) and pyroxenite with 87Sr/86Sr = 0.70309, 143Nd/144Nd = 0.51289, 206Pb/204Pb = 20.03, 207Pb/204Pb = 15.62, 208Pb/204Pb = 39.84 (HIMU-type endmember). Mixing of melts from these endmembers in proportions ranging from 70% peridotite and 30% pyroxenite to 28% peridotite and 72% pyroxenite can generate the compositions of the most primitive Gran Canaria shield stage lavas. Combining our results with those from the low silica rocks from the western Canary Islands [Gurenko et al. (2009) Enriched, HIMU-type peridotite and depleted recycled pyroxenite in the Canary plume: a mixed-up mantle. EPSL 277: 514-524], at least four distinct components are required. We propose that they are (1) HIMU-type pyroxenitic component (representing recycled ocean crust of intermediate age) from the plume center, (2) HIMU-type peridotitic component (ancient recycled ocean crust stirred into the ambient mantle) from the plume margin, (3) depleted, MORB-type pyroxenitic component (young recycled oceanic crust) in the upper mantle entrained by the plume, and (4) EM-type peridotitic component from the asthenosphere or lithosphere above the plume center.
    Description: This work was supported by the Wolfgang Paul Award of the Alexander von Humboldt Foundation (to AVS), the Max Planck Society, DFG grants SCHM 250/64, 82-1 and HA3097/2 (to HUS, KH and FH), the Russian Basic Research Foundation (grant 06-05-65234 to AVS) and the Russian Academy of Sciences.
    Keywords: Canary Islands ; Gran Canaria ; ODP Leg 157 ; Olivine ; Mantle plume ; Peridotite ; Pyroxenite ; Radiogenic isotopes ; Ocean crust ; Recycling
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/vnd.ms-excel
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © Elsevier B.V., 2009. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Earth and Planetary Science Letters 277 (2009): 514-524, doi:10.1016/j.epsl.2008.11.013.
    Description: The Earth’s mantle is chemically and isotopically heterogeneous, and a component of recycled oceanic crust is generally suspected in the convecting mantle [Hofmann and White, 1982. Mantle plumes from ancient oceanic crust. Earth Planet. Sci. Lett. 57, 421-436]. Indeed, the HIMU component (high μ = 238U/204Pb), one of four isotopically distinct end-members in the Earth’s mantle, is generally attributed to relatively old (≥1-2 Ga) recycled oceanic crust in the form of eclogite/pyroxenite, e.g. [Zindler and Hart, 1986. Chemical geodynamics. Ann. Rev. Earth Planet. Sci. 14, 493-571]. Although the presence of the recycled component is generally supported by element and isotopic data, little is known about its physical state at mantle depths. Here we show that the concentrations of Ni, Mn and Ca in olivine from the Canarian shield stage lavas, which can be used to asses the physical nature of the source material (peridotite versus olivine-free pyroxenite) [Sobolev et al., 2007. The amount of recycled crust in sources of mantle-derived melts. Science 316, 412-417], correlate strongly with bulk rock Sr, Nd and Pb isotopic ratios. The most important result following from our data is that the enriched, HIMU-type (having higher 206Pb/204Pb than generally found in the other mantle endmembers) signature of the Canarian hotspot magmas was not caused by a pyroxenite/eclogite constituent of the plume but appears to have been primarily hosted by peridotite. This implies that the old (older than ~1 Ga) ocean crust, which has more evolved radiogenic isotope compositions, was stirred into/reacted with the mantle so that there is not significant eclogite left, whereas younger recycled oceanic crust with depleted MORB isotopic signature (〈1 Ga) can be preserved as eclogite, which when melted can generate reaction pyroxenite.
    Description: This work was supported by Wolfgang Paul Award, Alexander von Humboldt Foundation, to AVS, the Max Planck Society, DFG grants SCHM 250/64 and 82-1, HA3097/2 to HUS, KH and FH, NSF Grant EAR-9105113 to KH, Russian Basic Research Foundation and Russian Academy of Sciences.
    Keywords: Canary Islands ; Mantle plume ; Pyroxenite ; Olivine ; Radiogenic isotopes
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 3
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    In:  Supplement to: Flower, Martin F J; Pritchard, R G; Schmincke, Hans-Ulrich; Robinson, Paul T (1983): Geochemistry of basalts: Deep Sea Drilling Project Sites 482, 483, and 485 near the Tamayo Fracture Zone, Gulf of California. In: Lewis, BTR; Robinson, P; et al. (eds.), Initial Reports of the Deep Sea Drilling Project (U.S. Govt. Printing Office), 65, 559-578, https://doi.org/10.2973/dsdp.proc.65.126.1983
    Publication Date: 2023-05-12
    Description: Recent investigations of the southern Gulf of California (22°N) on Leg 65 of the Deep Sea Drilling Project (DSDP) allow important comparisons with drilled sections of ocean crust formed at different spreading rates. During Leg 65 the Glomar Challenger drilled seven basement holes at sites forming a transect across the ridge axis near the Tamayo Fracture Zone. An additional site was drilled on the fracture zone itself, where a small magnetic "diapir" was located. Together with the material from Site 474 (drilled during Leg 64) the cores recovered at these sites are representative of the upper basaltic and sedimentary crust formed since the initial opening of the Gulf. The pattern of magmatic accretion at the ridge axis is conditioned by the moderate to high rate of spreading (~6 cm/y.) and comparatively high sedimentation rates that now characterize the Gulf of California. In terms of spreading rate, this region is intermediate between the "superfast" East Pacific Rise axis to the south (up to 17 cm/y.) and the slow-spreading Mid-Atlantic Ridge (2-4 cm/y.) both of which have been extensively studied by dredging and drilling.
    Keywords: Deep Sea Drilling Project; DSDP
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 4
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    In:  Supplement to: Viereck, L G; Simon, M; Schmincke, Hans-Ulrich (1986): Primary composition, alteration, and origin of Cretaceous volcaniclastic rocks, East Mariana Basin (Site 585, Leg 89). In: Moberly, R; Schlanger, SO; et al. (eds.), Initial Reports of the Deep Sea Drilling Project, Washington (U.S. Govt. Printing Office), 89, 529-553, https://doi.org/10.2973/dsdp.proc.89.121.1986
    Publication Date: 2023-05-12
    Description: An upper Aptian to middle Albian series of volcaniclastic rocks more than 300 m thick was drilled at Site 585 in the East Mariana Basin. On the basis of textural and compositional (bulk-rock chemistry, primary and secondary mineral phases) evidence, the volcaniclastic unit is subdivided into a lower (below 830 m sub-bottom) and an upper (about 670-760 m) sequence; the boundary in the interval between is uncertain owing to lack of samples. The rocks are dominantly former vitric basaltic tuffs and minor lapillistones with lesser amounts of crystals and basaltic lithic clasts. They are mixed with shallow-water carbonate debris (ooids, skeletal debris), and were transported by mass flows to their site of deposition. The lower sequence is mostly plagioclase- and olivine-phyric with lesser amounts of Ti-poor clinopyroxene. Mineralogical and bulk-rock chemical data indicate a tholeiitic composition slightly more enriched than N-MORB (normal mid-ocean ridge basalt). Transport was by debris flows from shallow-water sites, as indicated by admixed ooids. Volcanogenic particles are chiefly moderately vesicular to nonvesicular blocky shards (former sideromelane) and less angular tachylite with quench plagioclase and pyroxene, indicating generation of volcanic clasts predominantly by spalling and breakage of submarine pillow and/or sheet-flow lavas. The upper sequence is mainly clinopyroxene- and olivine-phyric with minor plagioclase. The more Ti-rich clinopyroxene and the bulk-rock analyses show that the moderately alkali basaltic composition throughout is more mafic than the basal tholeiitic sequence. Transport was by turbidity currents. Rounded epiclasts of crystalline basalts are more common than in the lower sequence, and, together with the occurrence of oxidized olivine pseudomorphs and vesicular tachylite, are taken as evidence of derivation from eroded subaerially exposed volcanics. Former sideromelane shards are more vesicular than in the lower sequence; vesicularity exceeds 60 vol.% in some clasts. The dominant clastic process is interpreted to be by shallow-water explosive eruptions. All rocks have undergone low-temperature alteration; the dominant secondary phases are "palagonite," chlorite/smectite mixed minerals, analcite, and chabazite. Smectite, chlorite, and natrolite occur in minor amounts. Phillipsite is recognized as an early alteration product, now replaced by other zeolites. During alteration, the rocks have lost up to 50% of their Ca, compared with a fresh shard and fresh glass inclusions in primary minerals, but have gained much less K, Rb, and Ba than expected, indicating rapid deposition prior to significant seafloor weathering.
    Keywords: Deep Sea Drilling Project; DSDP
    Type: Dataset
    Format: application/zip, 11 datasets
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  • 5
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    In:  Supplement to: Jenner, G A; Hertogen, J; Sachtleben, T; Schmincke, Hans-Ulrich (1985): Isotopic and trace element composition of basalts from Sites 556-559 and 561-564: Constraints on some processes affecting their composition. In: Bougault, H; Cande, SC; et al. (eds.), Initial Reports of the Deep Sea Drilling Project, Washington (U.S. Govt. Printing Office), 82, 501-507, https://doi.org/10.2973/dsdp.proc.82.126.1985
    Publication Date: 2023-05-12
    Description: Sr and Nd isotopic composition of 23 basalts from Sites 556-559 and 561-564. are reported. The 87Sr/86Sr ratios in fresh glasses and leached whole rocks range from 0.7025 to 0.7034 and are negatively correlated with the initial 143Nd/ 144Nd compositions, which range from 0.51315 to 0.51289. The Sr and Nd isotopic compositions (in glasses or leached samples) lie within the fields of mid-ocean ridge basalts (MORB) and ocean island basalts (OIB) from the Azores on the Nd-Sr mantle array/fan plot. In general, there is a correlation between the trace element characteristics and the 143Nd/144Nd composition (i.e., samples with Hf/Ta〉7 and (Ce/Sm)N〈1 [normal-MORB] have initial 143Nd/144Nd〉0.51307, whereas samples with Hf/Ta〈7 and (Ce/Sm)N〉1 (enriched-MORB) have initial 143Nd/144Nd compositions 〈0.51300). A significant deviation from this general rule is found in Hole 558, where the N-MORB can have, within experimental limits, identical isotopic compositions to those found in associated E-MORB. The plume-depleted asthenosphere mixing hypothesis of Schilling (1975), White and Schilling (1978) and Schilling et al. (1977) provides a framework within which the present data can be evaluated. Given the distribution and possible origins of the chemical and isotopic heterogeneity observed in Leg 82 basalts, and some other basalts in the area, it would appear that the Schilling et al. model is not entirely satisfactory. In particular, it can be shown that trace element data may incorrectly estimate the plume component and more localized mantle heterogeneity (both chemical and isotopic) may be important.
    Keywords: Deep Sea Drilling Project; DSDP
    Type: Dataset
    Format: application/zip, 3 datasets
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  • 6
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    PANGAEA
    In:  Supplement to: Hertogen, J; Sachtleben, T; Schmincke, Hans-Ulrich; Jenner, G A (1985): Trace element geochemistry and petrogenesis of basalts from Deep Sea Drilling Project Sites 556-559 and 561-564. In: Bougault, H; Cande, SC; et al. (eds.), Initial Reports of the Deep Sea Drilling Project, Washington (U.S. Govt. Printing Office), 82, 449-457, https://doi.org/10.2973/dsdp.proc.82.122.1985
    Publication Date: 2023-05-12
    Description: Forty-three samples from DSDP Holes 556-559 and 561-564 were analyzed for rare earth elements (REE), Sc, Cr, Co, Hf, Ta, and Th by instrumental neutron activation analysis. The recovered basalts range from those depleted in light REE (LREE) to those enriched in LREE. The two types of basalts occur together in Holes 558 and 561. The depleted basalts have remarkably constant La/Yb, La/Sm, and La/Ti ratios and apparently derive from a large, homogeneous, mantle source underneath a segment (1200 km long) of the Mid-Atlantic Ridge. The almost twofold variation in the concentrations of incompatible trace elements in the depleted basalts is primarily due to different degrees of batch partial melting. The variation of highly to moderately incompatible elements in the Leg 82 enriched basalts can be successfully explained in terms of source mixing between depleted mantle sources and alkaline or nephelinitic magmas similar to Azores Islands magmas. However, the correlation of LREE enrichment with distance from the Azores Triple Junction is tenuous at best, and the enriched alkaline component is probably not directly related to the Azores volcanism.
    Keywords: Deep Sea Drilling Project; DSDP
    Type: Dataset
    Format: application/zip, 2 datasets
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