ISSN:
0009-2940
Keywords:
Bicyclo[3.2.0]hepta-1,3-dienyl complexes
;
Ring slippage
;
Cycloadditions
;
Cobalt complexes
;
DSC
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The title reaction, which was detected by a comparison of the DSC analysis of title compound 2 with that of the corresponding bicyclo[3.3.0]octa-1,3-dienyl complex 3, takes place at 200°C with various dienophiles (dimethyl fumarate, dimethyl maleate, diphenylethyne, N-methylmaleinimide). 3,4-Dimethylenecyclopentenyl complex 12 most likely is the key intermediate of the reaction.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260724
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