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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Chromatographia 39 (1994), S. 520-528 
    ISSN: 1612-1112
    Schlagwort(e): Column liquid chromatography ; New bonded phases ; 13C and29Si CP-MAS NMR ; DRIFT ; ESCA
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary A variety of olefins were bonded to silaceous supports through a hydride modified substrate. The products were then examined by13C and29Si solid state-NMR with cross-polarization (CP) and magic angle spinning (MAS). Information about the surface was also obtained by diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) and the related photoelectron spectroscopic technique (ESCA). Carbon analysis on bonded silicas was carried out and surface coverage was calculated. Confirmation of the organic groups bound to the silica support was possible. The hydride intermediate is shown to be a versatile material for bonding a wide variety of organic moieties to silica surfaces.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2013-08-09
    Beschreibung: Author(s): E. Christensen, P. Coloma, and P. Huber We investigate the minimal performance, in terms of beam luminosity and detector size, of a neutrino factory to achieve a competitive physics reach for the determination of the mass hierarchy and the discovery of leptonic C P violation. We find that a low luminosity of 2×10 20 useful muon decays per y... [Phys. Rev. Lett. 111, 061803] Published Thu Aug 08, 2013
    Schlagwort(e): Elementary Particles and Fields
    Print ISSN: 0031-9007
    Digitale ISSN: 1079-7114
    Thema: Physik
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2019-01-25
    Beschreibung: Thermal emission spectroscopy is useful for identifying mineralogies including carbonates, sulfates, and phosphates. Each of these groups of minerals has a distinct emissivity profile that allows for general identification (e.g., carbonate). Laboratory data are being collected that suggest the potential for determining specific composition of these minerals (e.g., calcite, magnesite). Previous studies of Mars suggest that the above groups of minerals should be present. On Mars fine-grained mineralogies are likely to be intimately mixed due to aeolian activity. Mixtures of calcite with palagonite will be studied to determine the volume percent requirement for salt identification and to understand the complexities of fine-grained mixtures observed by thermal emission. Further work with mixtures will include sulfate and phosphate mineralogies.
    Schlagwort(e): INORGANIC AND PHYSICAL CHEMISTRY
    Materialart: Lunar and Planetary Inst., Twenty-Fourth Lunar and Planetary Science Conference. Part 3: N-Z; p 1505-1506
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2019-01-25
    Beschreibung: The mean particle diameter of surficial units on Mars has been approximated by applying thermal inertia determinations from the Mariner 9 Infrared Radiometer and the Viking Infrared Thermal Mapper data together with thermal conductivity measurement. Several studies have used this approximation to characterize surficial units and infer their nature and possible origin. Such interpretations are possible because previous measurements of the thermal conductivity of particulate materials have shown that particle size significantly affects thermal conductivity under martian atmospheric pressures. The transfer of thermal energy due to collisions of gas molecules is the predominant mechanism of thermal conductivity in porous systems for gas pressures above about 0.01 torr. At martian atmospheric pressures the mean free path of the gas molecules becomes greater than the effective distance over which conduction takes place between the particles. Gas particles are then more likely to collide with the solid particles than they are with each other. The average heat transfer distance between particles, which is related to particle size, shape and packing, thus determines how fast heat will flow through a particulate material.The derived one-to-one correspondence of thermal inertia to mean particle diameter implies a certain homogeneity in the materials analyzed. Yet the samples used were often characterized by fairly wide ranges of particle sizes with little information about the possible distribution of sizes within those ranges. Interpretation of thermal inertia data is further limited by the lack of data on other effects on the interparticle spacing relative to particle size, such as particle shape, bimodal or polymodal mixtures of grain sizes and formation of salt cements between grains. To address these limitations and to provide a more comprehensive set of thermal conductivities vs. particle size a linear heat source apparatus, similar to that of Cremers, was assembled to provide a means of measuring the thermal conductivity of particulate samples. In order to concentrate on the dependence of the thermal conductivity on particle size, initial runs will use spherical glass beads that are precision sieved into relatively small size ranges and thoroughly washed.
    Schlagwort(e): INORGANIC AND PHYSICAL CHEMISTRY
    Materialart: Lunar and Planetary Inst., Twenty-Fourth Lunar and Planetary Science Conference. Part 3: N-Z; p 1175-1176
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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