ISSN:
0009-2940
Keywords:
Iodocarbene, addition to alkenes
;
endo1-Selectivity
;
Cyclooctadiene
;
Cyclooctatetraene
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
New Observations Concerning the Stereoselectivity of Monoiodocarbene AdditionsContrary to our earlier claim, CHI gives endo/exo isomer mixtures with cyclooctene. However, only endo1-iodo compounds 7, 8, 10-12 are obtained from COD and COT. Tricyclic compound 7 rearranges partially to bicyclic 9, X-ray structure determinations of 7 and 9 were performed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260229
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