ISSN:
0009-2940
Keywords:
Acyloin condensation
;
Cyclohexane derivatives
;
Triphenylene derivatives
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A one-pot synthesis of a sixfold functionalized dodecahydro-triphenylene 2 with D3 symmetry starting from 1,2,3,4,5,6-hexakis(eq)(ethoxycarbonylmethyl)cyclohexane (1) is described. The new and straightforward approach to this tetracyclic ring system is based on a triple intramolecularly occurring acyloin condensation by using sodium in the presence of chlorotri-methylsilane.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250145
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