ISSN:
1572-8854
Keywords:
Crystal structure
;
platinum
;
xanthate
;
square planar
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The crystals of Pt(S2COEt)2 are orthorhombic, Pbca, with (at 20°C)a=7.799(3),b=7.368(6),c=20.588(7) Å,D cale=2.46g cm−3 forZ=4. The platinum atom resides on a crystallographic center of inversion and is bound to the four sulfur atoms of the xanthato ligand in a square planar geometry. The Pt−S distances are 2.313(6) and 2.320(7) Å with an intraligand S−Pt−S angle of 75.1(2)°.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01668236
Permalink