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  • Crystal chemistry  (1)
  • 1980-1984  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 114 (1983), S. 267-272 
    ISSN: 1434-4475
    Keywords: Nitrate group ; Crystal chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die geometrische Analyse sorgfältig verfeinerter Kristallstrukturen anorganischer Nitrate zeigt, daß schwache Aplanaritäten dieser Gruppe — d. h. solche mit einem Abstandd des Stickstoffs von der Ebene der drei Sauerstoffe bisd ∼ 0,02 Å — keineswegs seltene Ausnahmen sind. Viel größere Aplanaritäten wurden zwar beschrieben oder ergeben sich aus den veröffentlichten Strukturdaten; alle Beispiele mitd〉0,05 Å scheinen jedoch einer Bestätigung zu bedürfen.
    Notes: Abstract Geometric analysis of carefully refined inorganic nitrate crystal structures shows that weak aplanarities of the NO3-group, i.e. with a distanced of the nitrogen atom from the plane defined by the three oxygen atoms up tod∼0.02 Å, are by no means rare exceptions. Much larger aplanarities have been reported to occur in some crystal structures or follow from the published structure data, but all examples withd〉0.05 Å seem to need confirmation.
    Type of Medium: Electronic Resource
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