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Controlling the selectivity of glassy carbon flow detectors using covalently attached monolayers (1997)

Downard, Alison J. ; Roddick, Alisa D.

Weinheim : Wiley-Blackwell

Electroanalysis 9 (1997), S. 693-698

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ISSN: 1040-0397

Keywords: Flow analysis ; Covalently modified glassy carbon electrodes ; Selectivity ; Monolayers ; Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Significant improvements in selectivity for amperometric detection in flow analysis are achieved at covalently modified glassy carbon electrodes. Flow detectors modified with p-alkylbenzene (alkyl = methyl, decyl) and p-phenylacetate monolayers demonstrate how selectivity may be obtained on the basis of solute hydrophobicity and charge. The modified electrodes are stable under hydrodynamic conditions and in aqueous and mixed aqueous/organic carrier streams.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/elan.1140090908

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