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On the second-moment condition of Stillinger and Lovett (1977)

Mitchell, D. J. ; McQuarrie, D. A. ; Szabo, Attila ; [et al.]

Springer

Journal of statistical physics 17 (1977), S. 15-20

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ISSN: 1572-9613

Keywords: Ornstein-Zernike equation ; direct correlation function ; electrolytes ; moment condition ; solutions ; Coulombic

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract The Stillinger-Lovett second-moment condition of electrolyte solutions is derived rigorously and simply from only some reasonable (but apparently never proven rigorously) assumptions concerning the asymptotic form of the direct correlation function and the Ornstein-Zernike equation. The derivation suggests that this condition is not the first member of a hierarchy of moment conditions and that there exists no simple result for a fourth-moment condition.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01089374

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