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  • Coral  (1)
  • DOC  (1)
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  • 1
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters, 46(9), (2019):4790-4798, doi:10.1029/2019GL081939.
    Description: The East Asian Monsoon (EAM) impacts storms, freshwater availability, wind energy production, coal consumption, and subsequent air quality for billions of people across Asia. Despite its importance, the EAM's long‐term behavior is poorly understood. Here we present an annually resolved record of EAM variance from 1584 to 1950 based on radiocarbon content in a coral from the coast of Vietnam. The coral record reveals previously undocumented centennial scale changes in EAM variance during both the summer and winter seasons, with an overall decline from 1600 to the present. Such long‐term variations in monsoon variance appear to reflect independent seasonal mechanisms that are a combination of changes in continental temperature, the strength of the Siberian High, and El Niño–Southern Oscillation behavior. We conclude that the EAM is an important conduit for propagating climate signals from the tropics to higher latitudes.
    Description: Thanks go to G. Williams, W. Tak‐Cheung, and J. Ossolinski. Thanks also go to V. Lee, S. H. Ng for coral sampling, and B. Buckley for conversations. This research was supported by the National Research Foundation Singapore NRF Fellowship scheme awarded to N. Goodkin (National Research Fellowship award NRFF‐2012‐03) and administered by the Earth Observatory of Singapore and the Singapore Ministry of Education under the Research Centers of Excellence initiative. The research was also supported by the Singapore Ministry of Education Academic Research Fund Tier 2 (award MOE2016‐T2‐1‐016). Data are available in Table S1 and the NOAA paleoclimate database.
    Keywords: East Asian Monsoon ; Coral ; Radiocarbon
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L18602, doi:10.1029/2012GL052974.
    Description: Marine dissolved organic carbon (DOC) is the largest reservoir of reduced carbon in seawater and persists up to 4,000–6,000 conventional radiocarbon (14C) years on average. Photochemical degradation has been suggested as a geochemical sink for these long-lived molecules, yet there have been no studies relating photochemical lability to the 14C-ages of surface DOC. We observed apparent second order (2°) kinetics with respect to DOC and a strong trend from Δ14C-enriched to depleted values during exhaustive photomineralization of surface marine DOC with high energy UV light. Geochemically, these results suggest that surface DOC is an isotopically-heterogeneous mixture of molecules for which photochemical lability and 14C ages are correlated. Photochemical mineralization may therefore be an important control on the persistence of 14C-depleted DOC in the ocean.
    Description: This study was supported under NSF grant OCE-0961980 to E. R. M. Druffel.
    Description: 2013-03-20
    Keywords: DOC ; Kinetics ; Photochemistry ; Radiocarbon
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/msword
    Format: text/plain
    Format: application/pdf
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