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Stanna-closo-dodecaborate: A Nucleophile in Transition Metal Chemistry (1999)

Wesemann, Lars ; Marx, Thiemo ; Englert, Ulli ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 1563-1566

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ISSN: 1434-1948

Keywords: Stannaborate cluster ; Transition metal complexes ; Tin ; Coordination modes ; Clusters ; Boron ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Reactions of the stannaborate salt [NBu4]2[SnB11H11] (1) with the organometallic electrophiles [CpFe(CO)2Br], [(C7H7)Mo(CO)2I], and [CpNi(PPh3)Cl] resulted in substitution of the halide to give the stannaborate coordination products [NBu4][CpFe(CO)2(SnB11H11)] (2), [NBu4][(C7H7)Mo(CO)2(SnB11H11)] (3), and [NBu4][CpNi(PPh3)(SnB11H11)] (4) in high yields. Single crystals of the air- and moisture-stable products have been characterized by X-ray crystal structure analyses.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

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