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The catalytic activity and defect structure of zinc chromate (1991)

Jackson, R. A. ; Catlow, C. R. A. ; Thomas, J. M.

Springer

Catalysis letters 8 (1991), S. 385-389

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ISSN: 1572-879X

Keywords: Computer modelling ; non-stoichiometry ; oxide catalysis

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Computer simulation techniques are used to develop defect models for the non-stoichiometric spinel with composition Zn1+xCr2−xO4 system. The results are used to provide an interpretation of the variation with composition of the catalytic activity of the monophasic material. We suggest that the increase in the catalytic activity with the Zn/Cr ratio is associated with an increased concentration of oxygen vacancies.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00764201

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