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  • Computational Chemistry and Molecular Modeling  (2)
  • General Chemistry  (2)
  • Poaceae  (2)
Collection
Keywords
Publisher
Years
  • 1
    Electronic Resource
    Electronic Resource
    Defoliation Affects Chemical Defenses in All Plant Parts of Rye Seedlings (1999)
    Springer
    Journal of chemical ecology 25 (1999), S. 491-499 
    Details
    ISSN: 1573-1561
    Keywords: Defoliation ; regrowth ; induced responses ; chemical defense ; hydroxamic acids ; rye ; Secale cereale ; Poaceae
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract The effect of defoliation and consecutive defoliation (condefoliation) of rye seedlings on the allocation patterns of biomass and hydroxamic acids (Hx) was evaluated five days after treatment. Growth of condefoliated seedlings was lower than that of defoliated and nondefoliated ones. Concentration of Hx decreased in shoots of condefoliated seedlings compared to nondefoliated ones, while concentration of Hx in root exudates increased. Allocation of Hx to roots and root exudates increased at the expense of allocation to the shoots in condefoliated seedlings. The ratio of Hx-aglucone to Hx-glucoside was higher in shoots of defoliated and condefoliated seedlings. The decrease in quantity of defense in shoots was accompanied by an increase in its quality, given that aglucones are more toxic than glucosides. The increase in concentration of Hx—an allelopathic compound also involved in mineral uptake by roots—in root exudates of condefoliated seedlings was suggested to lead to an advantage in the acquisition of resources for the regeneration of lost biomass.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1020945602297
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  • 2
    Electronic Resource
    Electronic Resource
    DIBOA in wild Poaceae: Sources of resistance to the Russian wheat aphid (Diuraphis noxia) and the greenbug (Schizaphis graminum) (1998)
    Springer
    Euphytica 102 (1998), S. 317-321 
    Details
    ISSN: 1573-5060
    Keywords: aphids ; cereal breeding ; DIBOA ; Diuraphis noxia ; hydroxamic acids ; pest resistance ; Poaceae ; Schizaphis graminum
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Hydroxamic acids are secondary metabolites typical of Poaceae that play a role in cereal resistance against pests and pathogens. The content of the hydroxamic acid aglucones DIBOA (2,4-dihydroxy-1,4-benzoxazin-3-one) and DIMBOA (2,4-dihydroxy-7-methoxy-1,4-benzoxazin-3-one) was evaluated in wild Poaceae belonging to the tribes Triticeae (genera Hordeum and Elymus) and Aveneae (genera Deschampsia and Phalaris). The concentration of DIBOA in seedling extracts of the wild barleys Hordeum chilense, H. brevisubulatum subsp. violaceum and H. bulbosum was negatively correlated with parameters related to performance of the cereal aphids Schizaphis graminum and Diuraphis noxia. The relevance of the results obtained for breeding programs aimed at increasing cereal resistance against aphids is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1018323121213
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  • 3
    Electronic Resource
    Electronic Resource
    Löwdin partitioning in a Lanczos basis: Applications to scattering states (1983)
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 23 (1983), S. 135-146 
    Details
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Methods are reported for construction of closed-form optical potentials that provide useful L2-basis-set approximations to the discrete and continuum Schrödinger states of self-adjoint Hamiltonian operators. The potentials are obtained employing information from a finite (Lanczos) reference space only, but nevertheless correspond to explicit summation over an infinite-dimensional remainder space. Connections are indicated between the Stieltjes-Tchebycheff orbital solutions of the resulting optical-potential Schrödinger problem and previously described corresponding moment-theory approximations to spectral densities and distributions. Use of a Lanczos basis insures that the orbital eigenvalues are generalized Gaussian or Radau quadrature points of the spectral density, and that their (reciprocal) norms provide the associated quadrature weights. Convergence of the orbitals in the limit of high order is obtained to Schrödinger eigenstates of finite norm in the discrete spectral region, and to scattering states of improper (infinite) norm in the essential portion of the spectrum. In finite orders the spatial characteristics of the Stieltjes-Tchebycheff orbitals correspond to spectral averages in the neighborhoods of the quadrature points over the correct Schrödinger states. Explicit closed-form expressions are obtained for the spectral content of individual orbitals in terms of orthogonal polynomials without reference to the correct Schrödinger states. A computational application to regular Coulomb l waves illustrates the nature and convergence of the development.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/qua.560230115
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  • 4
    Electronic Resource
    Electronic Resource
    Stieltjes orbitals for molecular photoexcitation and ionization spectra: N → Vσ and N → V π resonance features in CO and H2CO cross sections (1984)
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 26 (1984), S. 719-734 
    Details
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Computational studies are reported of Stieltjes orbitals for Hilbert-space descriptions of discrete and continuum molecular electronic eigenstates. Particular attention is focused on the identification of N → V π(π → π*) and N → Vσ(σ → σ*) intravalence contributions to photoexcitation and ionization spectra in CO and H2CO molecules. Three-dimensional graphical representations of appropriate Stielties orbitals serve to identify the σ → σ* transitions of Mulliken as photoionization resonances above threshold in these compounds, whereas the corresponding π → π* contributions are spectrally localized as familiar discrete excited states. The development illustrates the nature and properties of Stieltjes orbitals, and demonstrates their utility in studies of both discrete and continuum excitation spectra on a common basis.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/qua.560260864
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  • 5
    Electronic Resource
    Electronic Resource
    Fabrikationskontrolle in der Konservenindustrie I. Vitamin C-Analyse von Tomatenkonzentraten (1948)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 60 (1948), S. 100-108 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19480600406
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  • 6
    Electronic Resource
    Electronic Resource
    Vorschläge zur rationellen Durchführung der chemischen Bestimmung von Vitamin C (1944)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 57 (1944), S. 159-161 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19440572109
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