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Mass-spectrometric characterization of isomeric NNCCN and NCNCN Ions and neutrals (1992)

Muedas, César A. ; Sülzle, Detlev ; Schwarz, Helmut

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 1517-1520

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ISSN: 0009-2940

Keywords: Interstellar chemistry ; Heterocumulenes ; Charge-reversal mass spectrometry ; Neutralization-reionization mass spectrometry ; Collisional activation ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Neutralization-reionization mass spectrometry as well as charge reversal and collisional activation experiments serve to distinguish and assign the connectivities NNCCN and NCNCN to isomeric pairs of anions, neutral radicals and cations of C2N3. Loss of N2 to generate C2N+ is the critical discriminant, and the assignment is further substantiated by subjecting these fragment ions to collisional activation experiments by using tandem-mass spectrometry facilities.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19921250631

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