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  • Cobalt complexes  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 2000 (2000), S. 683-691 
    ISSN: 1434-1948
    Keywords: Calix[4]arenes ; Bipyridines ; Podands ; Cobalt complexes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Introduction of one or two 2,2′-bipyridine units at the upper rim of the calix[4]arene platform was performed by means of the Wittig reaction. The resulting alkenes were hydrogenated to give two new bipyridyl-based calixarene podands, which were studied as ligands for CoII cation. The mono-bipyridyldichlorocobalt complex was notably fully characterised by 1H-NMR and X-ray crystal structure analyses, which confirmed the tetrahedral coordination mode involving the bipyridyl subunit and the two chlorine atoms around the cobalt centre.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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