ISSN:
1434-1948
Keywords:
Phosphorus
;
Pn
;
C5H3(SiMe3)2 ligands
;
Cobalt
;
Coordination chemistry
;
Crystallography
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The thermal or photochemical reaction of [Cp′′Co(CO)2] (1) [Cp′′ = C5H3(SiMe3)2-1,3] with white phosphorus (P4) gives [{Cp′′Co}2(P5-P5){CoCp′′}2] (2) and [{Cp′′Co}3P4(μ-CO)] (3) as well as [{Cp′′Co}2(μ-η2:η2-P2)2] (4). Cobalt complexes 2, 3, and 4 have been characterized by an X-ray crystal-structure determination.
Type of Medium:
Electronic Resource
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