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Polar Effects in Halogen Abstraction Reactions of Alkyl Radicals (1992)

Giese, Bernd ; Hartung, Jens

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 125 (1992), S. 1777-1779

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ISSN: 0009-2940

Keywords: Polar effects ; Radical clock ; Cobaloximes, alkyl ; Radicals, alkyl ; Chlorine abstraction ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: In a series of structurally similar alkyl radicals 1a-c the tertiary 1,1-dimethyl-5-hexenyl radical 1c reacts 30 times faster with carbon tetrachloride than the primary 5-hexenyl radical 1a. The reactivity of the secondary 1-methyl-5-hexenyl radical 1b aligns itself in between the primary and the tertiary radical 1a and 1c. The results indicate that the increasing nucleophilicity of the alkyl radicals is the major factor contributing to the reactivity.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19921250734

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