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Some Reactions of the Chloromethyl trans-β-Styryl Sulfone Carbanion (1997)

Ma̧kosza, Mieczyslaw ; Krylova, Irina

Weinheim : Wiley-Blackwell

Liebigs Annalen 1997 (1997), S. 2337-2340

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ISSN: 0947-3440

Keywords: Carbanions ; Chloromethyl β-styryl sulfone ; Nitroarenes ; Phase-transfer catalysis ; Vicarious nucleophilic substitution ; Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The chloromethyl trans-β-styryl sulfone carbanion reacts with benzaldehyde and acrylonitrile under phase-transfer catalysis conditions to give 2-phenyl-3-(trans-β-styrylsulfonyl)oxirane and bis(2-cyanoethyl)chloromethyl trans-β-styryl sulfone, respectively, and with nitroarenes to form the products of vicarious nucleophilic substitution of hydrogen.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jlac.199719971122

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