ISSN:
0021-8995
Schlagwort(e):
Chemistry
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Maschinenbau
,
Physik
Notizen:
For perhaps the first time, the dynamics of liquid-liquid phase separation was studied by time-resolved mechanical spectrometry in order to establish the relationship between blends' properties and the phase structures during spinodal decomposition (SD). The selected system was chlorinated polyethylene (CPE)/ethylene-vinyl acetate copolymer (EVA). It was found that in the early and intermediate stage of SD, the storage modulus (G′) and the loss modulus (G″) increase with time after the initiation of the isothermal phase separation; in the later stage, G′ and G″ decrease as phase separation proceeds. An entanglement fluctuation model was presented to manifest this phenomenon; it was found that the rheological behavior agrees well with the expections of the model in the early stage. For the later stage, the reduction of G′ and G″ can be attributed to the increment of phase-domain size. © 1993 John Wiley & Sons, Inc.
Zusätzliches Material:
10 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/app.1993.070500811
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