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  • 1
    Electronic Resource
    Electronic Resource
    Electrochemical and electron spectroscopic investigations of iron surfaces modified with thiols (1990)
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 16 (1990), S. 278-282 
    Details
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: In order to develop new composite materials between reactive metals and polymers, it is proposed to place organic monomers at the metal/polymer phase boundary, which can be coupled by covalent/ionic bonds to reactive centres of the metal substrate and later by covalent bonds to the polymer itself. As a first step, the model system iron/n-decanethiol (n-decylmercaptan, C10H21SH) has been investigated by AES and XPS. It is shown that the mercaptan binds to metallic clean iron surfaces through the sulphur atom, probably by cleavage of the S—H bond. The S 2p3/2 peak has a binding energy of 162.4 ± 0.2 eV. Anodic polarization and ageing in the laboratory atmosphere do not oxidize these chemisorbed molecules; the oxidation reactions of the substrate are suppressed too. After cyclovoltammetry (-1.0 VSHE≤ U ≤ + 0.6 VSHE), better oriented chemisorbed molecules are packed more densely on top of the surface.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/sia.740160158
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  • 2
    Electronic Resource
    Electronic Resource
    Über die Existenz des Oxoniumperchlorats (1924)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 440 (1924), S. 200-202 
    Details
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.19244400119
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  • 3
    Electronic Resource
    Electronic Resource
    Neue Hochvakuummethoden in der Chemie (1921)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 34 (1921), S. 149-151 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19210343005
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