ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Time-resolved vibrational chemiluminescence from HF has been recorded following the production of F atoms by the pulsed laser photolysis (λ = 266 nm) of F2 in the presence of HCl, CH4, and CF3H. In the first two cases, experiments have been conducted by observing emission from HF(ν = 3) at four temperatures from 295 to 139 K. Rate constants have been determined over this range of temperature for the reactions of F atoms with HCl and CH4 and of CH3 radicals with F2, and for the relaxation of HF(ν = 3) by HCl and CH4. The reaction of F atoms with CF3H is slower than those with HCl and CH4 and measurements on the emission from HF(ν = 2) have been used to infer rate constants for reaction and relaxation only at 295 K. © 1994 John Wiley & Sons, Inc.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550260804
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