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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 596-606 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Optimal jacket-fluid temperature profiles for tubular Nylon 6 reactors (in the presence of radial gradients of temperature and concentration) have been obtained using an algorithm based on the continuous minimum principle developed for a distributed parameter system. A gradient search technique has been devised and implemented for obtaining these optimal profiles. The optimal temperature profiles are found to be at the maximum permissible temperature, Tmax, at the beginning of the reactor and then slowly decrease to the minimum permissible temperature, Tmin, near the end of the reactor. The effect of varying several parameters is also studied. The desired value of the chain length and the reaction time are found to be the parameters which effect the optimal profiles most significantly.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 27 (1989), S. 616-623 
    ISSN: 0749-1581
    Keywords: 13NMR ; Tertiary arsine ; Aminoarsonium ions ; Arsonium ions ; Aminoarsines ; 1H NMR ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 13C and 1H NMR spectral data for a homologous series of tertiary arsines (R3As, where R = Me, Et, n-Pr and Ph), aminoarsines and arsonium and aminoarsonium salts are reported and discussed. In nearly all cases, quaternization of the tertiary arsine to its corresponding arsonium or aminoarsonium salt causes a decrease in the magnitude of δc. These results are compared with those from an analogous study on the quaternization of tertiary phosphines, R3P. A discussion of the factors that affect the relative magnitudes of δc and R3As and R3P is given. Hammett-Taft dual substituent parameter analysis was used to show that the positive charge on the arsenic in the atomatic quaternary salts is delocalized by an inductive mechanism. The 1H NMR spectra of the n-propyl- and phenyl-containing compounds are non-first order. The δH and nJ(HH) values were determined by iterative computer analysis. Likewise, the nJ(CH) values for the phenyl carbons of [Ph3AsNH2]Cl and [Ph3AsNHMe]Cl were determined from the coupled 13C NMR spectra.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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