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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 10 (1964), S. 548-550 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 294-303 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The major types of instabilities which can alter a given two-phase flow pattern or lead to the breakup of a liquid film are delineated, and their physical mechanisms are discussed. Existing stability criteria are correlated to these basic types, and their application and limitations with respect to actual problems are indicated. Basic areas requiring further study are outlined.A criterion for determining the breakup length of a liquid film is developed which gives an indication of whether a given instability will lead to low frequency and high amplitude pressure and inventory pulsations. Such phenomena may be undesirable.Two new aspects of importance to the problem of film instability are introduced which have not been previously studied. These are rotation of the fluids and large disturbances in the flow. Their possible influence on the problem is discussed.
    Additional Material: 11 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 1281-1294 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The steady formation of fibers in the air-gap wet-spinning process is analyzed, in which solidification of the fiber material is brought about by the diffusional exchange of solvent and nonsolvent in a coagulation bath. The concentration profile within the fiber is determined, and a simple model is given for the change of the material behavior with changing concentration. The material behavior of the uncoagulated spinning solution is described by a constitutive model for viscoelastic liquids that allows the incorporation of a relaxation-time spectrum. The behavior of the solidified fiber is described by a model for rubberlike elastic solids. The effects of variable fiber temperature and skin friction on the fiber motion are also taken into account. The computed velocity profiles are compared to experimental data. These data were obtained by spinning three samples of nominally identical spinning solutions. Even though the theoretically predicted profiles agree well with those obtained with the first two samples, they completely fail to do so for the third. This failure is attributed to the unexpected extreme sensitivity of the model predictions to the width of the dynamic spectrum that is used to infer the relaxation-time spectrum. It is also found that the velocity profile depends rather strongly on the initial conditions for the stress.
    Additional Material: 14 Ill.
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  • 4
    ISSN: 1434-1948
    Keywords: Coordination modes ; Cyclophanes ; Macrocycles ; Sandwich complexes ; Solid-state structures ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A novel mode of containment for metal ions which participate in longer-range interactions with aryl rings (≥ 2.5 Å) is demonstrated in the preorganized cylindrical host 1. Three equatorial sulfur atoms in 1 hold metals in a trigonal planar ligand field between two apical benzene centroids at an M-Ar distance of about 3 Å. Evidence of an interaction between the π electrons and the metals is gained by 1H NMR spectroscopy of the complexes, and support for the general description of metal-arene contacts in the 2.5-3.5 Å range as ‘‘bonds’’ is derived from a statistical study of η6-coordination in the solid state. Crystal structures of [Ag(1)]BF4 and [Cu(1)]BF4 confirm the first examples of arene AgI and CuI sandwich complexation and indeed the only structurally characterized CuI-aryl centroid interaction. The two isomeric tris-sulfoxides derived from 1 show less tendency to interact with metals ions.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 1004-1008 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is presented for getting approximate solutions to the Orr-Sommerfeld equation for free surface flows. The method consists of replacing the velocity, normally a function of distance from the wall, by its value at the free surface while the second derivative of the velocity is kept at its true value. This permits a simple solution to the equation and the eigenvalues can then be determined by a simple and rapid numerical technique. Comparison of this approximate solution for the flow of a thin film on a vertical wall with existing exact numerical solutions and with analytical results valid only for small Reynolds numbers shows the approximation to be quite accurate for most practical values of the parameters and suggests that the method will be useful in investigating the stability of related flows.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 309-312 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 19-28 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical model for the process of bubble and drop formation in flowing liquids, applicable for both terrestrial and microgravity environments, has been developed by using a force balance. The contact angle variation at the nozzle due to the bubble motion and the added mass coefficient of the bubble moving through a pipe have been theoretically analyzed, considering bubble motions during its expansion and detachment stages. Predictions of bubble size of the model show satisfactory agreement with available experimental results in the case of normal gravity. The effects of the nondimensional variables on bubble and drop size are evaluated in microgravity conditions. In microgravity, the bubble is detached from the nozzle only by the liquid flow drag, and in the region of low liquid velocity the bubble size becomes much larger than that in normal gravity.
    Additional Material: 9 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 378-379 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 150-153 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A novel type of piezometer used to measure the compressions of liquids from 20° to 300°C. and from 1 to 4,000 kg./sq. cm. is described. The accuracy anticipated is 4 parts in 10,000.
    Additional Material: 4 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 13 (1967), S. 91-96 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the measurement of the absorption of carbon dioxide gas by a series of oil drops moving down a vertical wire the variables studied are drop frequency, oil viscosity, wire size, and column length. A model is proposed which assumes that the gas is absorbed by almost stagnant liquid film between and covering the drops, that the film is subsequently mixed with a drop as it moves past, and that the dissolved gas is carried from the column in circulating loops of liquid within the drops. The model leads to an equation which correlates the data and gives a good approximation to the slope of the line.
    Additional Material: 5 Ill.
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