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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 55 (1997), S. 339-347 
    ISSN: 0006-3592
    Keywords: detergent based aqueous two phase systems ; phase separation by sedimentation ; phase separation by centrifugation ; separation of detergent based aqueous phase systems ; biomass influence ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Detergent based aqueous two-phase systems have several specific properties, e.g., extreme small density differences between the two liquid phases (0.003-0.005 g/cm3), low interfacial tensions (5-10 μN/m) and complex rheological behavior of the product containing detergent-rich phase, which make processing difficult. We describe the successful separation of these aqueous two-phase systems in the pilot scale (1-20 kg) in the presence and absence of microbial cells, either by settling under gravity or in centrifugal separators. The performance of self-desludging liquid-liquid separators and of a nozzle separator was analyzed in detail to judge large scale application. With a feed rate of 16 L/h, stable operation was possible in the desludging machine. Up to 56 L/h could be processed with very close control of the hydrodynamic balance. In a small nozzle separator, feed rates of 90 L/h could be realized, but the purity of the separated phases and the yield of the top phase was slightly lower than in the liquid-liquid separator. The presence of surface-active components in the feed may alter the separation characteristics of the phase systems significantly. © 1997 John Wiley & Sons, Inc. Biotechnol Bioeng 55: 339-347, 1997.
    Additional Material: 5 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 127 (1923), S. 43-67 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 200 (1931), S. 113-132 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1. Ungeachtet des starken Anwachsens der Viskosität bei der Polymerisation verläuft sie unimolekular.
    Additional Material: 10 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 16 (1955), S. 101-120 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Divinylbenzene (48%)/ethylvinylbenzene copolymer was converted to a series of pyrolytic derivatives. Enough of the carbon bond network remained intact throughout thermal rearrangement and condensation to retain the original gross shape of the copolymer in the final polymer carbon. Although a carbon residue (6% by weight) was obtained by direct heating of the copolymer, yields were increased eightfold by preoxidation or prechlorination. Such an alteration of thermal degradation is obviously a complex process involving both “inhibition,” in the ordinary sense, and a considerable contribution toward an increased valence network density. As a consequence, the average molecular weight of volatile fragments evolved during carbonization is inversely proportional to the oxygen content of the original hydrocarbon polymer. Pyrolysis of divinylbenzene copolymer, containing 18% oxygen, resulted in a 50% volume shrinkage, 50% weight loss, and a 100% density gain. Unless these data are attributable to extensive microporosity, it is difficult to account for the sorption of up to 3 cc. of helium gas per gram of polymer carbon at 30°C. and 600 mm. pressure; and calculated surface areas as large as 1400 sq.m./g. Abrupt changes in the progress of polymer carbon formation occurred between 600 and 700°C. The residue became rigid; vigorous evolution of volatile products, principally hydrogen, suddenly diminished; and paramagnetic resonance absorption (unpaired electron concentration) dropped about tenfold while d.c. resistivity decreased 106 ohm cm. In this region, also, x-ray patterns were most diffuse, exhibiting no maxima characteristic of carbon scattering in either hydrocarbons or condensed rings. Finally, the x-ray patterns of polymer carbon intermediates became less diffuse in samples prepared at 700°C. or above. Yet, scattering indicated the presence of crosslinked graphitic layers of such stability that reordering or true graphitization did not occur at 2400°C.
    Additional Material: 18 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 222 (1884), S. 354-374 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 462 (1928), S. 267-283 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 1 (1984), S. 66-73 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Besides the knowledge of material constants of the homogeneous phases of a disperse system, a good understanding of its geometrical properties is necessary for describing physical processes. In order to characterize the shape of the interface between solids and pore space with respect to the irregularities in all orders of magnitude, the fractal dimension has proved to be an informative parameter. By this study the theory of fractal dimensions, in three-dimensional space originally limited to topological curves, surfaces and volumes, is extended into physical properties like specific surface, tortuosity, porosity and formation factor with “physical” dimensions -1 or 0 as an exponent of the unit of length. The typical properties of the true fractals are transferable to some of these derived parameters. This leads to power laws describing the dependence of the particular measure on the resolution length. With special models, which seem to be of widespread validity in nature, petrophysical considerations lead to further power laws for the rest of the physical parameters, dependent on discrete length parameters such as grain radius and pore radius. By determination of the exponents of such independent power laws, a better particle characterization is possible, as the fractal dimension of the surface alone may be misleading, especially when the grain size of the particles is not uniform.
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Process Safety Progress 16 (1997), S. 25-31 
    ISSN: 1066-8527
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Waste-derived fuel is an environmentally friendly method for destroying waste and recovering the energy value it contains. The fuel is characterized as a mixture of various solvents with a flashpoint in the flammable range. In addition to these solvents, the waste fuel contains solid material. During the transfer of this material to storage tanks, some of the solid material is is left behind in the tankers and rail cars. The ideal solution to remove this solid material is to wash the tank vehicle with the same waste fuel. With the waste fuel being in the flammable range, there is a concern about the washing operation causing ignition due to static electricity.Scaled experiments were conducted to assess the potential for static electricity to cause ignition. Although several ignition mechanisms were assessed, this paper is concerned with the charged mist caused by the high velocity solvent jet impinging on the tank wall. Isopropyl alcohol, mixed xylenes, and mineral spirits were evaluated. An aerosol electrometer was used to measure charge per unit volume of mist sampled. Discharge generation was assessed using an analytical model which estimates electric field corresponding to measured charge density for various configurations.
    Additional Material: 8 Ill.
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  • 10
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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