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Relative reactivities of polymer radicals in vinyl polymerizations (1954)

Herbst, Ralph L. ; Martin, Robert E.

Hoboken, NJ : Wiley-Blackwell

Journal of Polymer Science 14 (1954), S. 391-395

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ISSN: 0022-3832

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The relative reactivities of polymer radicals in vinyl polymerization have been correlated semiquantitatively according to the Alfrey-Price Q′ and e scheme. Polystyrene radicals are arbitrarily assigned a Q′r value of unity. The relative reactivities of other polymer radicals are then characterized by the Q′ and e values of the parent monomers. This is shown by data concerned with copolymerization, homopolymerization, and chain transfer. It is proposed that the dispersion forces of London are the predominant influence in chain transfer reactions of polymer radicals with solvents.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1954.120147607

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