ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The solvatochromic comparison method is used to unravel solvent polarity and hydrogen bonding effects on a variety of NMR spectral shifts and coupling constants. Solvent effects are rationalized in terms of the solvatochromic parameters π*, δ, α and β. Properties analyzed include 19F shifts of 5-fluoroindole, 1H shifts of fluorodinitromethane, tert-butanol, phenol, 2-methylbut-1-en-3-yne, and thioacetamide, 1H and 13C shifts and J(13C1H) coupling constants of chloroform, 13C shifts of acetone, 15N shifts of pyridine, 15N and 29Si shifts of 1-methylsilatrane, and some J(119Sn,C,19F) coupling constants of polyalkyltin compounds.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270140612
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