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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 18 (1974), S. 2279-2285 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Stable dispersions are prepared by free-radical polymerization of methyl methacrylate in aliphatic hydrocarbons containing poly(dimethylsiloxane) modified with mercaptoalkyl side groups. The particles are pictured as being stabilized by a protective layer of solvated poly(dimethylsiloxane). Some important features of the polymerization are described.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 50 (1993), S. 57-66 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The tensile strain rate effect in tensile strength and elongation at break for a series of filled dummy hydroxy-terminated polybutadiene (HTPB) propellant binders was studied. The data were obtained at various tensile strain rates from 10-4 to 10-1 s-1 on two types of specimens at room temperature. The “high velocity ductility” behaviour, which is qualitatively similar to those of unfilled elastomers, was revealed. This means that the breaking strain increases markedly at elevated strain rates. For “Bukkon-type” and rod-shaped specimens, test results are consistent with each other. The fact that the increased filled solids level leads to a decreased breaking elongation capability and an increased tensile strength was obviously found. © 1993 John Wiley & Sons, Inc.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 17 (1992), S. 51-58 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It has been demonstrated that addition of small amounts of the newly developed neutral polymeric bonding agents (NPBA's) to energetic propellants such as HMX/PEG/NG composites causes strong filler reinforcement. The mechanism of this reinforcement occurs through interfacial effects, and not because of an overall increase in the crosslink density of the binder. It has been demonstrated directly that the NPBA's have a favorable relative affinity for HMX and concentrate at the solid surface during mixing. All the experimental evidence supports the theory that highly crosslinked polymeric shells form around the HMX particles and chemically bond to the binder matrix during the cure, thus causing an increase in the initial modulus. Furthermore, these shells appear to eliminate the weak, soft layers around the particles, and hence filler reinforcement persists up to much higher elongation than without addition of NPBA. Based on the filler reinforcement observed, the simple one-step procedure of incorporating our NPBA is almost as effective as the more costly process of precoating the particles.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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