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A gel point method for the estimation of overall apparent activation energies of polymerization (1960)

Gough, L. J. ; Smith, I. T.

New York, NY [u.a.] : Wiley-Blackwell

Journal of Applied Polymer Science 3 (1960), S. 362-364

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ISSN: 0021-8995

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics

Notes: The gel time, measured under isothermal conditions, may be taken as a measure of the overall rate of polymerization of a given system under certain circumstances. This enables us to estimate the Arrhenius activation energy from such measurements. A simple piece of apparatus is described which has been used to measure the overall activation energy of some epoxy resin polymerizations. The agreement with previously published data is reasonable.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/app.1960.070030914

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