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  • 1
    Electronic Resource
    Electronic Resource
    Catalytic oxidation of hydrogen chloride in a fluid bed reactor (1973)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 1009-1016 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Deacon reaction (HCI + 1/4 O2 ⇋ 1/2 Cl2 + 1/2 H2O) was studied in a catalytic fluid bed reactor. Reaction rates found from measurements in differential and integral reactors were represented by the Langmuir-Hinshelwood type rate equation. Considering the effect of catalysts in the dilute phase, it was found that conversions in a fluid bed reactor can be calculated without any modifying parameters. It is pointed out that the wake fraction, which has been necessary to consider for fast reactions in a fluid bed reactor, is attributed to the dilute phase effect.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690190518
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  • 2
    Electronic Resource
    Electronic Resource
    Axial distribution of reactivity inside a fluid-bed contactor (1976)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 354-361 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The axial destribution of reactivity inside a fluid-bed contactor is studied for the hydrogenation of ethylene. The reactivity is large near the surface of the dense phase. The significant effect of the dilute phase, or the free board region, is verified experimentally, and the contact efficiency in the transition zone and in the dilute phase is obtained. The contact efficiency was approximated by ηc = 1 - 0.75 (∊e/∊ede)0.4. The temperature rise in the dilute phase is measured in the small reactor. The transition zone between the dense and dilute phases is almost isothermal, but it is found that temperature increases in the dilute phase.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690220218
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  • 3
    Electronic Resource
    Electronic Resource
    Relative contribution of variables affecting the reaction in fluid bed contactors (1974)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 1087-1096 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Simplified expressions to calculate the extent of reaction in a fluid bed show good agreement with the experimental data of Lewis et al. (1959) and Swaay and Zuiderweg (1972). The contribution of the dilute phase seems more important than that of the jetting zone or reaction factor (Hatta number) in usual fluid bed operations. The effect of the dilute phase is discussed. It is profitable to use the dilute phase for the consecutive isothermal and endothermic reaction, but unprofitable for the exothermic reaction. These characteristics depend upon the nature of reactions and careful considerations as to the choice of the gas velocity, particle characteristics, and reactor design will be necessary.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690200605
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  • 4
    Electronic Resource
    Electronic Resource
    Recovery of uranium from seawater using amidoxime hollow fibers (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 411-416 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A novel amidoxime-group-containing adsorbent of hollow-fiber form (AO-H fiber) was prepared by radiation-induced graft polymerization of acrylonitrile onto a polyethylene hollow fiber, followed by chemical conversion of the produced cyano group to an amidoxime group. Distribution of the amidoxime group was uniform throughout the hollow-fiber membrane. The fixed-bed adsorption column, 30 cm in length and charged with the bundle of AO-H fibers, was found to adsorb uranium from natural seawater at a sufficiently high rate: 0.66 mg uranium per g of adsorbent in 25 days.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690340308
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  • 5
    Electronic Resource
    Electronic Resource
    Some aspects of reaction rate of pyruvate reduction by dextra-bound NADH and lactate dehydrogenase (1982)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 24 (1982), S. 1211-1216 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260240517
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  • 6
    Electronic Resource
    Electronic Resource
    Taxol (paclitaxel) production using free and immobilized cells of Taxus cuspidata (1997)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 53 (1997), S. 214-219 
    Details
    ISSN: 0006-3592
    Keywords: Taxol ; plant cell culture ; continuous production ; immobilization ; Taxus cuspidata ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The production characteristics for Taxol (paclitaxel) using free and immobilized cells of Taxus cuspidata were investigated in a perfusion culture bioreactor. Although the cell growth was inhibited by higher dilution rates, the specific production rate of Taxol was increased by perfusion compared with that using batch operation. Perfusion cultures using a nylon-mesh cell separator for free suspension cells showed similar production profiles to those obtained using immobilized cells. Continuous Taxol production was successfully obtained at an approximate specific production rate of 0.3 mg/g DCW (dry cell weight) per day for up to 40 days. © 1997 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Immobilized Coffea arabica cell culture using a bubble-column reactor with controlled light intensity (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 42 (1993), S. 494-502 
    Details
    ISSN: 0006-3592
    Keywords: Coffea arabica cells ; immobilized cells ; light intensity ; bubble-column reactor ; alkaloid production ; viable cell distribution ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Coffea arabica cells immobilized by calcium alginate gel were photocultured using a bubble-column reactor under controlled light intensity. This process was carried out after their alkaloid productivity was improved by increasing the cell density in the initial gel matrix and preculturing the immobilized cells in the dark prior to light irradiation. The cells were grown in the form of a biofilm on gel beads, producing 100 mg/L of purine alkaloids in a 24-day batch culture. Alkaloid production was relatively constant with respect to light intensity changes, and also cell growth was not suppressed much at high light intensity, with these behaviors being different from those obtained using suspended cells. These phenomena are explained by estimating the light intensity gradient within the cell-immobilizing particles and by measuring the viable cell distribution within them. It subsequently suggests that the subsurface cells affect both the production and growth behaviors. © 1993 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260420413
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  • 8
    Electronic Resource
    Electronic Resource
    Capture of microbial cells on brush-type polymeric materials bearing different functional groups (1997)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 53 (1997), S. 523-528 
    Details
    ISSN: 0006-3592
    Keywords: radiation-induced graft polymerization ; microbial cell capture ; tertiary amino group ; coexisting functional group ; capturing rate constant ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A brush-type microbial-cell-capturing polymeric material was prepared by radiation-induced grafting of an epoxy-group-containing monomer, glycidyl-methacrylate (GMA), onto a polyethylene-based fiber. The epoxy ring (EO) of GMA was opened with different degrees of introduction of diethylamine (DEA). The residual epoxy group was hydrophilized by ethanolamine (EA). The prepared DEA membranes with coexisting EO or EA groups were tested for their ability to capture Staphylococcus aureus and Escherichia coli cells. The DEA membrane (2.7 mol/kg of product of DEA group density) with coexisting EO groups (DEA-EO membrane) exhibited good S. aureus-cell-capturing ability with a capturing rate constant of 1.82 × 10-6 m/s, whereas the DEA membrane with coexisting EA groups (DEA-EA membrane) retarded capturing abilities for both S. aureus and E. coli cells. © 1997 John Wiley & Sons, Inc. Biotechnol Bioeng 53: 523-528, 1997.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Affinity extraction of proteins with a reversed micellar system composed of Cibacron Blue-modified lecithin (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 58 (1998), S. 58-64 
    Details
    ISSN: 0006-3592
    Keywords: affinity extraction ; crude soybean lecithin ; reversed micelles ; Cibacron Blue F-3GA ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Crude soybean lecithin was used as a novel surfactant to form reversed micelles in n-hexane. Cibacron Blue F-3GA (CB) was directly immobilized to the reversed micelles by a two-phase reaction. The reversed micellar system without CB showed low solubilizing capacity for low molecular weight proteins, lysozyme, and cytochrome c due to the weak electrostatic interactions. The introduction of CB significantly increased the solubilization of lysozyme because of its affinity binding to CB but showed no effect on the solubilization of cytochrome c since it did not bind to CB. Although bovine serum albumin had an affinity for CB, it was not extracted to the reversed micelles containing CB because its high molecular weight resulted in a significant steric hindrance effect. Thus the reversed micellar system had a high selectivity resulting from both biospecific and steric hindrance effects. The extraction yield of lysozyme decreased significantly with increasing ionic strength. Therefore, the back extraction of lysozyme was carried out using a stripping solution with an ionic strength of 0.865 mol/L. The overall recovery yield of lysozyme after back extraction could be increased to 87% by stripping for 2 h. The recovered lysozyme exhibited an activity equivalent to native lysozyme, and its secondary structure was also unchanged. © 1998 John Wiley & Sons, Inc. Biotechnol Bioeng 58:58-64, 1998.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Diffusivity of oxygen into carriers entrapping whole cells (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 34 (1989), S. 55-58 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effective diffusivity of oxygen, De, in Ca-alginate and PVA-SbQ gels was measured using a two-chamber vessel with a membrane between the two chambers. The effect of cell density, Cc, on De in Ca-alginate gels was studied. The effective diffusivity of oxygen decreased with increasing cell density, to Cc = 170 kg dry cells/m3 gel. The dependency of De on cell density was discussed in terms of a random-pore model. The model correlated well with experimental data, i.e., kDe/D0 = 0.86(1 - 1.47 × 10-3 Cc)2. Here, k is the partition coefficient, and D0 is diffusivity in water.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260340107
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