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  • 1
    Electronic Resource
    Electronic Resource
    Some observations on glass transition on poly(ethylene terephthalate) filaments in the necking regionSPRC Contribution No. 95. (1984)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 4395-4397 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1984.070291267
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  • 2
    Electronic Resource
    Electronic Resource
    Effect of alkali on filaments of poly(ethylene terephthalate) and its copolyesters. II. Presence of quaternary ammonium salt in the alkali-bath (1990)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 39 (1990), S. 893-907 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Influence of alkyl (C12-C14)-dimethyl-benzyl ammonium chloride in the solution of sodium hydroxide on the hydrolysis of poly(ethylene terephthalate) (PET), anionically modified poly(ethylene terephthalate) copolyster (CDP), and block polymer of poly(ethylene terephthalate)-poly(ethylene glycol) (EDP), has been studied under a variety of proportions, concentrations, time and temperature of reaction, M : L ratio, etc. Mechanical properties of treated polymeric materials are evaluated. Hydrolysis of two polymers in the same bath is compared with that in separate baths.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1990.070390410
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  • 3
    Electronic Resource
    Electronic Resource
    Effect of alkali on filaments of poly(ethylene terephthalate) and its copolyesters (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 38 (1989), S. 1447-1468 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The alkali hydrolysis of poly(ethylene terephthalate), anionic copolymer of poly(ethylene terephthalate), and block copolymer of poly(ethylene terephthalate)-poly(ethylene glycol) is investigated under a variety of conditions of alkali concentration in aqueous bath, additives, time, and temperature. Measurements of loss in weight, linear density, breaking load, tenacity, elongation to break apart from intrinsic viscosity, fiber density, COOH-end group content, diameter of filaments, and scanning electron micrographs have been analyzed to identify the differences in the action of alkali on these polymer materials.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1989.070380804
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  • 4
    Electronic Resource
    Electronic Resource
    Properties of filaments spun from poly(ethylene terephthalate) chips containing PET-dustSPRC Contribution No. 89. (1983)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 3619-3628 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It is observed that the thick portions in a poly(ethylene terephthalate) (PET) filament differ from the rest in their solution viscosity and birefringence, indicating that they are caused by the inhomogeneity of the polymer melt. To identify the cause of the latter, the PET chips are critically examined. It is found that the waferlike tails on the edge of the PET chips and PET-dust have slightly higher viscosity than the chips. The behavior of the chips and the dust during drying and melt spinning are examined to find whether the dust becomes postpolymerized during drying. Such dried PET-dust exhibits substantially different melting behavior than the chips. The filaments spun from the mixture of chips and PET-dust exhibit significantly higher nonuniformity in properties than the filaments spun from the chips only. It is concluded that the PET-dust entering the extruder with the chips can cause thick portions in the filaments.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1983.070281203
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  • 5
    Electronic Resource
    Electronic Resource
    Kinetics of transesterification of dimethylene terephthalate with ethylene glycolSPRC Contribution No. 106. (1985)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 30 (1985), S. 205-219 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: There is a disagreement about the order of reaction of transesterification of DMT with EG. The reactivity of the two ester groups is not compared yet. The transesterification of DMT and MHET is studied to establish the kinetics of the process. Attempts are made to treat the kinetic data on a mathematical model for third-order reaction.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1985.070300117
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