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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 1304-1310 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Thermal conductivity measurements were made for the dissociating system 2 NO2 ⇋ 2NO + O2. Experiments were made at temperatures from 548° to 792°K. and pressures from 1 to 30 atm. Under these conditions the chemical reaction is in a nonequilibrium state, and the rate of energy transport is limited by the rates of the forward and reverse reactions. Experimental results agreed very well with a theoretical model based on a linearized reaction rate expression. Using the thermal conductivity results, it was also possible to determine the chemical kinetic constants for the reaction.
    Additional Material: 10 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 32 (1986), S. 4709-4718 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: To improve the performance of Nylon 4 membranes, this study attempts to utilize 60Co γ-ray irradiation which induces vinyl monomers to be grafted onto Nylon 4 membranes for desalination purposes. Sodium styrene sulfonate, acrylamide, vinylacetate, and styrene are the grafting monomers. The transport properties and mechanical strength of the γ-ray irradiation-grafted Nylon 4 membranes are studied. Both the water flux and salt rejection of sodium styrene sulfonate-grafted membranes increase significantly, compared to Huang's results. The other grafted membranes also show increased salt rejection.
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 1539-1547 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The photochemical polymerization rates of isoprene, ethyl methacrylate, and of styrene in various aromatic solvents were measured. The average lifetimes of propagating radicals were measured by the rotating sector method. The polymerization rate constants, Kp, were determined and compared with dipole moments (μ) and Hammett σ constants for the aromatic solvents. Linear correlations of log(kp/kp, benzene) vs. μ and σ were obtained.
    Additional Material: 6 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 2613-2620 
    ISSN: 0887-624X
    Keywords: polydimethylsiloxane ; poly(methyl methacrylate) ; block copolymer ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Azo group-containing polydimethylsiloxanes (PDMS-ACP), macroazoinitiators, were prepared by polycondensation reaction of 4,4′-azobis-4-cyanopentanoyl chloride (ACPC) with hydroxybutyl-terminated polydimethylsiloxane (PDMS) of varying molecular weights. The activation energy (Ea), activation enthalpy (ΔH
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 3313-3318 
    ISSN: 0887-624X
    Keywords: polydimethylsiloxane ; photoinitiator ; methyl methacrylate ; rate constants ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics of the free radical photopolymerization of methyl methacrylate (MMA) initiated by azo-containing polydimethylsiloxane (PSMAI) and azobisisobutyronitrile (AIBN) was investigated. The greater polymerization rate Rp in MMA/PSMAI systems may be due to the higher value of the initiation rate Ri and the lower value of the termination rate constant kt than that in MMA/AIBN system. The reaction orders with respect to initiators PSMAI decreased with an increase in polydimethylsiloxane chain length (SCL) in PSMAI. The observed deviations in polymerization rate from rate equation could be explained in terms of primary radical termination. The photoinitiator efficiency Φ of initiators decreased with increase in SCL, while the ratio of the rate constants for chain termination and chain initiation by primary radical increased with SCL. The fraction β of primary radicals entering into termination in MMA/PSMAI systems were larger than that in MMA/AIBN system. © 1996 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 3337-3343 
    ISSN: 0887-624X
    Keywords: aged energetic copolymer ; thermal stability ; activation energy ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The thermal decomposition behavior of the aged tetrahydrofuran copolymers with 3-azidomethyl-3′-methyloxetane (AMMO) or 3-nitratomethyl-3′-methyloxetane (NMMO) were studied by thermogravimetry and evolved gas analysis, and compared with aged polytetrahydrofuran (poly-THF) The thermal stability decreased in the order poly-THF 〉 poly-AMMO-THF-AMMO 〉 poly-NMMO-THF-NMMO, whereas the range of temperature for decomposition increased in the order poly-THF 〈 poly-AMMO-THF-AMMO 〈 poly-NMMO-THF-NMMO. The apparent activation energies of the degradation for polymers with ageing, calculated by the Ozawa method, were smaller than that without ageing. © 1996 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 679-685 
    ISSN: 0887-624X
    Keywords: polymethylphenylsilane ; polymeric photoinitiator ; rate constants ; monomer dipole moment ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The rates of photochemical polymerization of styrene (St), p-chlorostyrene (Cl-St), methyl methacrylate (MMA), and butyl methacrylate (BMA) with polymethylphenylsilane (PMPS) as an initiator were measured. Polymethylphenylsilane is photodegrated to form silyl radicals that may initiate polymerization of vinyl monomers. Rate constants kp and kt have been determined for these systems. A good correlation (log P = α + βμ) of the resonance stabilization (P) of the chain radicals and the dipole moment (μ) of the monomers is observed for these polymerization systems. This equation may be used to estimate the resonance stabilization (P) of a monomer and the polymerization rate constant (kp). © 1996 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 36 (1998), S. 2521-2530 
    ISSN: 0887-624X
    Keywords: poly(methylphenylsiloxane) ; poly(methyl methacrylate) ; graft copolymer ; spin-spin relaxation ; degradation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly(methylphenylsiloxane)-poly(methyl methacrylate) graft copolymers (PSXE-g-PMMA) were prepared by condensation reaction of poly(methylphenylsiloxane)-containing epoxy resin (PSXE) with carboxyl-terminated poly(methyl methacrylate) (PMMA), and they were characterized by gel permeation chromatography (GPC), infrared (IR), and 29Si and 13C nuclear magnetic resonance (NMR). The microstructure of the PSXE-g-PMMA graft copolymer was investigated by proton spin-spin relaxation T2 measurements. The thermal stability and apparent activation energy for thermal degradation of these copolymers were studied by thermogravimetry and compared with unmodified PMMA. The incorporation of poly(methylphenylsiloxane) segments in graft copolymers improved thermal stability of PMMA and enhanced the activation energy for thermal degradation of PMMA. © 1998 John Wiley & Sons, Inc. J. Polym. Sci. A Polym. Chem. 36: 2521-2530, 1998
    Additional Material: 11 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 9 (1986), S. 409-410 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; Reversed phase ; MAPS phase ; Explosives ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 10
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The retentions of 11 explosives on two commercially RP-18 and Si 100 stationary phases and one prepared 3-[9′-(10′-methylanthryl)]- propylsilane stationary phase (MAPS-phase) were examined by modified mobile phases. The evaluation of these three stationary phases results as follows: (1)Most explosives were effectively separated on a column of MAPS-phase not only with methanol/water (75/25-85/15) as mobile phase but also with n-hexane/dichloromethane (75/25) as mobile phase.(2)Few explosives were effectively separated on a column of RP-18 with methanol/water (75/25-85/15) as mobile phase.(3)The separation of most explosives on Si 100 was achieved only under normal phase condition such as n-hexane/dichloromethane (75/25) as mobile phase.
    Additional Material: 1 Ill.
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