ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The kinetics of decarboxylative dechlorination of N-chloroalanine were studied at 25° in aqueous HCl solutions covering the pH range 1.4 to 2.8. These data were compared with literature results, and were interpreted in terms of first-order reactions of the cationic, uncharged, and anionic forms of the reactant. Pressure effect studies on the reaction of the anionic species yielded a volume of activation estimate of + 50 ± 3 cm3 mol-1. This result is consistent with a concerted fragmentation process. © 1996 John Wiley & Sons, Inc.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.1
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