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  • 1
    ISSN: 1573-0662
    Keywords: FTIR ; 3D Modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Vertical column abundances of HCl, ClONO2, HF and HNO3 have been obtained from infrared solar absorption measurements made at Aberdeen, UK (57°N, 2°W) during the periods January 13 1994 - May 8 1994 and November 23 1994 - April 19 1995. The measurements reveal the partitioning of inorganic chlorine (Cly) inside and outside the polar vortex during these two winter and spring periods. Stratospheric temperatures within the northern polar vortex during 1993/94 were not cold throughout January and most of February. The measurements reported here suggest that following a brief period of chlorine activation in late February and early March, the active chlorine within the vortex recovered rapidly to form ClONO2 resulting in in-vortex ClONO2 columns of 7 × 1015 molecules cm-2. In contrast, measurements during January 1995 suggest extensive invortex activation with in-vortex HCl + ClONO2 as low as 3.6×1015 molecules cm-2. High day-to-day variability in the ClONO2 columns observed during February is evidence for the transport of ClONO2 rich air from high to mid latitudes during the late winter. The implications for mid latitude O3 loss are discussed. A preliminary comparison of the HCl, ClONO2, and HNO3 column data from winter 94/95 with a three-dimensional chemical transport model shows that the model generally reproduces well the day-to-day variability and absolute magnitude of the observed columns, especially for HNO3 outside of the vortex.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of atmospheric chemistry 30 (1998), S. 131-140 
    ISSN: 1573-0662
    Keywords: FTIR ; 3D Modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract We outline how ground-based Fourier transform infrared (FTIR) measurements of stratospheric trace species, obtained with high temporal resolution, could be used to detect filaments of polar vortex air at mid-latitudes and therefore test high spatial resolution chemical transport models (CTMs). Vertical column abundances of HCl, ClONO2, HNO3, N2O and HF have been obtained from FTIR solar absorption measurements made throughout the day from Aberdeen, UK (57°N, 2°W) on several days during winter/spring 1993/94 and 1994/95. The short-timescale (∼ 2 hours) variability observed in the columns is attributed to real atmospheric variations and is often associated with the passage of high latitude air over Aberdeen. This is confirmed by 3D modelling studies which qualitatively reproduce and rationalise the observed changes in the column data on January 19 1994, January 20 1995 and February 26 1995. We describe the viewing geometry of ground-based FTIR measurements and we suggest a measurement strategy which should maximise the information retrieved on horizontal gradients in stratospheric trace species columns from FTIR measurements.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 1089-1102 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this investigation, experimentally measured radial birefringence profiles are compared to internal stress distributions as predicted by a mathematical model. A direct indicator of the degree of molecular orientation, fiber birefringence, is found to correlate well with the stress distributions as calculated from radial temperature variations. In an initial study of glass fibers, no radial birefringence profiles are found, indicating that any residual stresses present are small. In polystyrene fibers, however, large radial variations in birefringence are observed and are shown to be directly related to the calculated internal stresses.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 31 (1959), S. 485-485 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 28 (1956), S. 505-506 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 31 (1959), S. 549-550 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 74 (1962), S. 83-83 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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