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  • 1
    ISSN: 1573-5117
    Keywords: reservoir impact ; serial discontinuity ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The downstream effects of impoundments on the chemistry of pristine and polluted stretches of the Buffalo River were investigated in the context of the Serial Discontinuity Concept (Ward & Stanford, 1983). Impoundments which received water from a near-pristine upper catchment caused alterations of the water quality which were consistent with the Serial Discontinuity Concept, and recovery to riverine conditions was within 2.6 to 18.4 km of the dam, depending on flow. Impoundments which received agricultural runoff and urban effluents generally caused an improvement in the water quality of the downstream reaches (with the exception of nitrate concentrations, which were higher in the tailwaters compared to inflowing water). Impoundments with polluted inflows therefore usually ‘reset’ the river towards its natural condition, rather than acting as perturbations. This represents a reversal of the Serial Discontinuity Concept described for pristine rivers. The downstream effects of impoundments on water chemistry therefore depend on the relative impact of other catchment perturbations. These disturbances become more severe during low flow, and it is during this time that the impoundments have the greatest effect on the river.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-5117
    Keywords: reservoir impact ; serial discontinuity ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The downstream effects of impoundments on the chemistry of pristine and polluted stretches of the Buffalo River were investigated in the context of the Serial Discontinuity Concept (Ward & Stanford, 1983). Impoundments which received water from a near-pristine upper catchment caused alterations of the water quality which were consistent with the Serial Discontinuity Concept, and recovery to riverine conditions was within 2.6 to 18.4 km of the dam, depending on flow. Impoundments which received agricultural runoff and urban effluents generally caused an improvement in the water quality of the downstream reaches (with the exception of nitrate concentrations, which were higher in the tailwaters compared to inflowing water). Impoundments with polluted inflows therefore usually ‘reset’ the river towards its natural condition, rather than acting as perturbations. This represents a reversal of the Serial Discontinuity Concept described for pristine rivers. The downstream effects of impoundments on water chemistry therefore depend on the relative impact of other catchment perturbations. These disturbances become more severe during low flow, and it is during this time that the impoundments have the greatest effect on the river.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-5117
    Keywords: macroinvertebrates ; water quality ; bio-indicators ; functional feeding groups
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The aim of this paper was to investigate the potential for using functional feeding groups (FFGs) as indicators of water quality conditions in rivers, using the Buffalo River, South Africa, as a specific example. Multivariate classification and ordination techniques were used to investigate species and FFG distributions in relation to a number of physico-chemical variables at 16 sites from the headwaters to the estuary of the Buffalo River. Two-way indicator species analysis (TWINSPAN) of species composition ranked most of the sites sequentially down the river, irrespective of water quality conditions. Ordination of FFGs from a set of riffle samples collected in mid-late summer showed only weak relationships between FFG distribution and water quality changes, except where variables changed sequentially down the river (e.g. pH and temperature). Individual species responses to water quality gradients were examined for nine riffle-dwelling species representing diverse FFGs. Following correspondence analysis of a matrix of environmental variables and species frequencies, some species showed strong associations with defined ranges of some variables. In particular, Adenophlebia auriculata (Leptophlebiidae, Ephemeroptera) from the headwater sampling site, was associated with low pH and low temperature. Simulium damnosum occurred under conditions of high turbidity, while Afronurus harrisoni was found under high concentrations of potassium, ammonium and nitrite ions. We conclude that although there was a distinct headwaters fauna in the Buffalo River, and sequential downstream changes in species composition, most FFGs (apart from shredders) were represented down the whole length of the river. FFG classifications are therefore unlikely to provide useful indications of water quality conditions in the Buffalo River. Using a categorical approach to classifying water quality variables, and by applying correspondence analysis to the resulting matrix, we recognised nine species that could be used to define water quality. These indicator species can be used to define tolerance ranges of the fauna for water quality conditions in different parts of the Buffalo river.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 50-64 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Monitoring and control of batch pulp digesters, which convert wood chips to pulp by Kraft process are discussed. The Kappa number, which represents the extent of delignification, is the key controlled variable, which cannot be measured on-line and must be estimated through secondary liquor measurements. Given a fixed batch time, the final Kappa number should be as close to the target Kappa number as possible, despite errors in the initial state estimates and input disturbances. To fulfill this objective, a state-observer-based model-predictive controller is designed using a detailed nonlinear dynamic model of the digester. The extended Kalman filter (EKF) using on-line measurements of various liquor characteristics is capable of recovering from significant errors in the initial state estimates. In addition, the EKF is shown to be robust to the errors in the covariance matrices and most model parameters, but quite sensitive to some model parameter errors. Coupled with the EKF, a finite-horizon model predictive controller (MFC) based on successive linearization of the nonlinear pulping model, is found to work efficiently for controlling the Kappa number and batch time.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2209-2224 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general formulation of the moving horizon estimator is presented. An algorithm with a fixed-size estimation window and constraints on states, disturbances, and measurement noise is developed, and a probabilistic interpretation is given. The moving horizon formulation requires only one more tuning parameter (horizon size) than many well-known approximate nonlinear filters such as extended Kalman filter (EFK), iterated EKF, Gaussian second-order filter, and statistically linearized filter. The choice of horizon size allows the user to achieve a compromise between the better performance of the batch least-squares solution and the reduced computational requirements of the approximate nonlinear filters. Specific issues relevant to linear and nonlinear systems are discussed with comparisons made to the Kalman filter, EKF, and other recursive and optimization-based estimation schemes.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 2813-2827 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A frequency-domain identification method for multivariable systems is presented. The method emphasizes accurate identification of the process's gain directionality that is shown to be important for feedback control. The method requires closed-loop testing in addition to conventional open-loop testing, and combines open-loop and closed-loop data such that the derived model matches both the system's frequency-response matrix and its inverse accurately. The method is used to identify a model for a nonideal high-purity distillation column and is shown to capture the gain directionality of the process more accurately than the conventional method.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
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