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  • 1
    Electronic Resource
    Electronic Resource
    Nomenclature of polymers (based on structure) (1989)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 2065-2070 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In the complete absence of a systematic polymer nomenclature, a scheme of nomenclature based on structure is proposed. The problem of naming a “mer” has been solved for an addition polymer by adding “ne” to the monomer name, the justification being on withdrawal of a π bond a monomer becomes a mer. To furnish completeness to the nomenclature, condensation polymers were included in the system. The present nomenclature system of polymers is very arbitrary. Some polymers are not chemically named, some named incorrectly, and there are some fantastic names. After pointing these out, the possible solutions were shown, encompassing a systematic discussion on nearly every type of polymer-linear, branched, or crosslinked-and copolymer (including block or graft), and plastic, fiber, or rubber, and stereospecific polymer. One or more names were proposed for different cases.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1989.080270624
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  • 2
    Electronic Resource
    Electronic Resource
    EXSENSEL - a rule-based approach to selection of sensors for process variables (1996)
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 19 (1996), S. 443-447 
    Details
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A novel expert-system-based method for selection of sensors for process variables is presented. EXSENSEL (expert system based sensor selection) deals with 12 process variables and currently has 94 rules in its knowledge base. Despite its large knowledge base, users have to answer a set of only a few questions regarding a particular process variable, which is selected from a menu of 12 variables. A general description of the chosen process variable can be viewed before invoking the rules. Once a sensor has been selected, a brief write up on that particular sensor is also available on user's request. EXSENSEL is the successor to TRANSELEX, which is a single expert system for selection of transducers in the area of temperature, pressure, and flow measurement.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ceat.270190510
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  • 3
    Electronic Resource
    Electronic Resource
    A dynamic mechanical study on unidirectional carbon fiber-reinforced polypropylene composites (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 831-840 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Fiber-reinforced polymer composites show high specific strength and stiffness. The alignment of reinforcing fibers results in anisotropy of the material. This anisotropic behavior has been studied through dynamic mechanical analysis of unidirectional carbon fiber-reinforced polypropylene (CFRPP) composites measured in both parallel and transverse directions to fiber arrangement. Several parameters such as storage modulus (E′), loss modulus (E″), loss factor or damping factor (tan δ), and complex viscosity (MU*) have been determined over a wide range of frequencies and at a fixed temperature. Relaxation and retardation spectra have been constructed for these composites. Modulus enhancement occurs due to stiffness imparted by the fiber and efficient stress transfer at the interface. Relaxation of the polymer matrix ceases with increase in the volume fraction of the fibers. α′-relaxation is observed for the composite having a 13% volume fraction of fibers and is ascribed to relaxation in the crystalline phase where the additional crystallinity arises out of the transcrystalline growth at the fiber-matrix interface. There exists a good correlation between theroretical curves with the experimental ones. Relaxation and retardation spectra and the dynamic parameters determined for these composites show a good correlation with the volume fraction of fibers as well as the direction of the applied load. © 1994 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1994.070510506
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  • 4
    Electronic Resource
    Electronic Resource
    Graft copolymerization of methyl methacrylate and natural rubber (1967)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 1603-1611 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Graft copolymerization of natural rubber and MMA was carried out in the presence of Bz2O2 or AIBN as thermal initiator and hydrogen peroxide or benzophenone as photosensitizer. From the overall copolymerization product, the rubber-PMMA graft copolymer fraction was isolated from unreacted rubber and free PMMA fractions and composition characterization of the separated fractions was done by determination of rubber unsaturation. The efficiency of grafting under different conditions has been calculated and compared.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1967.070110821
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  • 5
    Electronic Resource
    Electronic Resource
    Novel liquid-in-pore configurations in membrane solvent extraction (1990)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 1592-1596 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690361018
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  • 6
    Electronic Resource
    Electronic Resource
    Saccharification of untreated agrowastes during mycelial growth of mushroom Termitomyces clypeatu on solid beds (1984)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 26 (1984), S. 188-190 
    Details
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260260211
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  • 7
    Electronic Resource
    Electronic Resource
    Synthesis and lysis of formate by immobilized cells of Escherichia coli (1992)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 39 (1992), S. 775-780 
    Details
    ISSN: 0006-3592
    Keywords: formate ; Escherichia coli ; formate hydrogenlyase ; cell immobilization ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Formate hydrogenlyase (FHL) activity was induced in a strain of Escherichia coli S13 during anaerobic growth in yeast extract-tryptone medium containing 100 mM formate. The cells obtained at the optimum growth phase were immobilized in 2.5% (w/v) agar gel when 50-60% of the whole cell FHL activity was retained. The immobilized FHL system had good storage stability and recycling efficiency. In the lysis of formate, an increase of formate concentration to 1.18M increased QH2 (initial) value of the immobilized cell, and subsequently cells, hydrogen evolution, in general, ceased after 6 to 8 of incubation, resulting in incomplete lysis of formate. Presence of small amount of glucose (28 mM) was more or less quantitatively lysed with concomitant disappearence of glucose from the medium. Synthesis of formate from hydrogen and bicarbonate solution by the immobilized cells was also characterized. Presence of glucose (10 mM) in 50 mM bicarbonate solution stimulated formate synthesis by immobilized cells. The pH optimum range, Km, and specific activity of the immobilized cells for the lysis of formate were 6.8-7.2 0.4M, and 66 mL/g cell-h, respectively. The cells could fix hydrogen to the extent of 24.4% (w/w) of its own wet cell mass in a 72-h reaction cycle. Potentiality of the immobilized FHL system for biotechnological exploitation was discussed.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260390710
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  • 8
    Electronic Resource
    Electronic Resource
    Metals sorption by chelating polymers: A unique role of ionic strength (1992)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 153-157 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690380116
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  • 9
    Electronic Resource
    Electronic Resource
    Ternary gas mixture separation in two-membrane permeators (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 529-539 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Single-stage separation of ternary gas mixtures of He, CO2, and N2 in a hollow-fiber permeator that simultaneously houses two different types of membranes, cellulose acetate and silicone rubber, was investigated. The two membranes have reverse selectivities with respect to He and CO2. Such a two-membrane permeator separates the feed into three streams, two permeates and one reject, each stream being enriched in a different component. The species permeabilities through each membrane were measured independently, and these values were utilized in a simulation that incorporates the fiber lumen pressure drops, the elastic deformation of the silicone capillaries, and the asymmetric structure of the CA membrane. Simulation results are compared with experimental data. Effects of flow pattern, relative permeation areas of the two membranes, permeate pressure ratios, feed composition, and membrane selectivities are studied. Advantages of the two-membrane scheme over the conventional permeators with only one kind of membrane are discussed.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690330402
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  • 10
    Electronic Resource
    Electronic Resource
    Modeling chromate ion-exchange processes (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 2019-2029 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In spite of chromate's very high selectivity at acidic pH, fixed-bed chromate-exchange processes always suffer from severe gradual breakthroughs of chromate during column runs. Earlier, Sengupta and Clifford confirmed that such a gradual breakthrough is an equilibrium phenomenon and provided the underlying ion-exchange mechanism. An algorithm, developed with the aid of the governing chromate ion-exchange mechanism, is presented here to predict the salient properties of chromate-exchange processes in a multicomponent system. The model predicts the gradual chromate breakthroughs during column runs fairly accurately and also accounts for other unusual characteristics of chromate ion exchange. Average separation factor models, often used for designing fixed-bed ion-exchange processes, are unable to predict the gradual breakthrough characteristics of a preferred component such as chromate.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690341211
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