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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 12 (1979), S. 391-392 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Isomeric cyclodiphosphazane selenides, R(X)P(NBu1)2P(Y)R (R=OMe or NMe2, X=Se, Y=lone pair; R=OMe or NMe2, X=Y=Se) display large differences (34-122 ppm) in 77Se chemical shift. The 77Se shifts of these and related amino derivatives are well to low field of the 77Se shifts of analogous acyclic phosphorus selenides.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 29 (1991), S. 813-824 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Wurtz-type coupling of a number of representative classes of substituted dichlorosilane monomers was investigated in considerable detail. Low temperature polymerization techniques, including ultrasonic activation, were also studied. Similarly, the effect of dipolar additives on the polymerization process was examined. The conclusions drawn from these studies provide some insight into the selection of useful polymerization conditions for the conversion of various monomer types into linear high polymers.
    Additional Material: 5 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 107-112 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A simple 13C-NMR method for the quantitative determination of polyflavonoid tannin characteristics was developed. The system is effective for use on concentrated (25-50%) solutions of natural and modified tannins. It allows the determination of the average degree of polymerization (DPn) of the polyflavonoid, resorcinol vs. phloroglucinol proportion of the A-ring and catechol vs. pyrogallol proportion of the B-ring. The results obtained are consistent with existing data determined by other techniques. The method was also tried with tannin extract that was modified to form thermosetting adhesive intermediates, and with tannin modified by sulfonation, a common commercial modification for these materials. The results were again consistent with what was expected. The method affords the possibility to follow by a simple technique the variations in DPn and MM̄n (number-average molecular weight) induced by chemical modifications of polyflavonoid tannin extracts and thus to correlate them with relevant structural modifications affecting these parameters. The method is not capable of distinguishing the relative proportions of the four important flavonoid units present in commercial polymeric tannin extract. It can only distinguish the relative proportions of (i) (procyanidins + prodelphinidins) vs. (profisetinidins + prorobinetinidins) and (ii) (prorobinetinidins + prodelphinidins) vs. (profisetinidins + procyanidins). © 1995 John Wiley & Sons, Inc.
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 1429-1437 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The crystal orientation distribution in injection-molded bars made from several polypropylene compounds has been investigated using pole figure analysis. The fillers used were glass fibers, chalk, and talc, and some compounds contained one filler and others contained glass fibers plus one or both of the others. All compounds showed strong orientation in the skin with the b-axis of the monoclinic crystals lying preferentially normal to the flow direction and in many cases parallel to the normal to the bar face. This normal direction orientation was very strong in compounds containing talc and is probably caused by crystals forming with their (010) planes on the talc platelet faces, which align themselves parallel to the mold face. Strong orientation persists into the interior of the moldings containing talc, whereas in the other compounds, the orientation at intermediate depths is much less pronounced than in the skin. © 1992 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
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  • 5
    Publication Date: 2019-07-13
    Description: Objective quantification of model performance based on metrics helps us evaluate the current state of space physics modeling capability, address differences among various modeling approaches, and track model improvements over time. The Coupling, Energetics, and Dynamics of Atmospheric Regions (CEDAR) Electrodynamics Thermosphere Ionosphere (ETI) Challenge was initiated in 2009 to assess accuracy of various ionosphere/thermosphere models in reproducing ionosphere and thermosphere parameters. A total of nine events and five physical parameters were selected to compare between model outputs and observations. The nine events included two strong and one moderate geomagnetic storm events from GEM Challenge events and three moderate storms and three quiet periods from the first half of the International Polar Year (IPY) campaign, which lasted for 2 years, from March 2007 to March 2009. The five physical parameters selected were NmF2 and hmF2 from ISRs and LEO satellites such as CHAMP and COSMIC, vertical drifts at Jicamarca, and electron and neutral densities along the track of the CHAMP satellite. For this study, four different metrics and up to 10 models were used. In this paper, we focus on preliminary results of the study using ground-based measurements, which include NmF2 and hmF2 from Incoherent Scatter Radars (ISRs), and vertical drifts at Jicamarca. The results show that the model performance strongly depends on the type of metrics used, and thus no model is ranked top for all used metrics. The analysis further indicates that performance of the model also varies with latitude and geomagnetic activity level.
    Keywords: Space Radiation
    Type: GSFC.JA.00400.2012 , Space Weather; 9; 1-17
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  • 6
    Publication Date: 2019-07-10
    Description: We present a multiwavelength analysis of the high-energy gamma-ray source 3EG J2006-2321 (l = 18 deg.82, b = -26 deg.26). The flux of this source above 100 MeV is shown to be variable on time scales of days and months. Optical observations and careful examination of archived radio data indicate that its most probable identification is with PMN J2005-2310, a flat-spectrum radio quasar with a 5GHz flux density of 260 mJy. Study of the V = 19.3 optical counterpart indicates a redshift of 0.833 and variable linear polarization. No X-ray source has been detected near the position of PMN J2005-2310, but an X-ray upper limit is derived from ROSAT data. This upper limit provides for a spectral energy distribution with global characteristics similar to those of known gamma-ray blazars. Taken together, these data indicate that 3EG J2006-2321, listed as unidentified in the 3rd EGRET Catalog, is a member of the blazar class of AGN. The 5-GHz radio flux density of this blazar is the lowest of the 68 EGRET-detected AGN. The fact that EGRET has detected such a source has implications for unidentified EGRET sources, particularly those at high latitudes (absolute value of b greater than 30 deg), many of which may be blazars.
    Keywords: Space Radiation
    Type: astro-ph/0112568-v1
    Format: application/pdf
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  • 7
    Publication Date: 2019-08-14
    Description: The 3rd EGRET Catalog contains 170 unidentified high-energy (E〉100 MeV) gamma-ray sources, and there is great interest in the nature of these sources. One means of determining sources class is the study of flux variability on time scales of days; pulsars are believed to be stable on these scales while blazars are known to be highly variable. In addition, previous work has led to the discovery of 2CG 135+01 and GRO J1838-04, candidates for a new high-energy gamma-ray source class. These sources display transient behavior but cannot be associated with any known blazars. These considerations have led us to conduct a systematic search for short-term variability in EGRET data, covering all viewing periods through cycle 4. Three unidentified sources show some evidence of variability on short time scales; the source displaying the most convincing variability, 3EG J2006-2321, is not easily identified as a blazar.
    Keywords: Space Radiation
    Type: Sep 15, 1999 - Sep 17, 1999; Portsmouth, NH; United States|EGRET Team Papers to be Published in the Proceedings of the Fifth Compton Symposium
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  • 8
    Publication Date: 2019-07-13
    Description: The source 3EG J1835+5918 was discovered early in the CGRO (Compton Gamma Ray Observatory) mission by EGRET as a bright unidentified gamma-ray source outside the galactic plane. Especially remarkable, it has not been possible to identify this object with any known counterpart in any other wavelengths band since then. Analyzing our recent ROSAT HRI observation, for the first time we are able to suggest X-ray counterparts of 3EG J1835+5918. The discovered X-ray sources were subject of deep optical investigations in order to reveal their nature and conclude on the possibility of being counterparts for this peculiar gamma-ray source.
    Keywords: Space Radiation
    Type: EGRET Team Papers to be Published in the Proceedings of the Fifth Compton Symposium|Sep 15, 1999 - Sep 17, 1999; Portsmouth, NH; United States
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  • 9
    Publication Date: 2019-07-13
    Description: During analysis of sources below the threshold of the third EGRET catalog, we have discovered a source, named GRO J1400-3956 based on the best position, with a remarkably steep spectrum. Archival analysis of COMPTEL data shows that the spectrum must have a strong turn-over in the energy range between COMPTEL and EGRET. The EGRET data show some evidence of time variability, suggesting an AGN, but the spectral change of slope is larger than that seen for most gamma-ray blazars. The sharp cutoff resembles the high-energy spectral breaks seen in some gamma-ray pulsars. There have as yet been no OSSE observations of this source.
    Keywords: Space Radiation
    Type: EGRET Team Papers to be Published in the Proceedings of the Fifth Compton Symposium|Sep 15, 1999 - Sep 17, 1999; Portsmouth, NH; United States
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  • 10
    Publication Date: 2019-07-13
    Description: Mrk 501 is the third TeV blazar with a known GeV component. Previous multiwavelength campaigns on Mrk 501 showed well correlated outbursts at x-ray and TeV energies with no significant activity at GeV energies. We present here new evidence suggesting GeV outbursts in Mrk 501 when the spectrum appears to be extremely hard. However, this outburst appears uncorrelated with emission at x-ray energies. The resulting spectral energy distribution suggests a sharp cut off in the high-energy emission beyond a few hundred GeV.
    Keywords: Space Radiation
    Type: Sep 15, 1999 - Sep 17, 1999; Portsmouth, NH; United States|EGRET Team Papers to be Published in the Proceedings of the Fifth Compton Symposium
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