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  • Chemistry  (16)
  • Polymer and Materials Science  (8)
  • 1
    Publication Date: 2021-07-24
    Description: This project has focused on better understanding the potential impact of On-Farm Flood Capture and Recharge (OFFCR) on groundwater quality pertaining to salts and nitrate and on assessing potential management opportunities. To achieve these goals, we used a combination of field and modeling studies. For the field study, soil cores were taken to a depth of 30 feet in replicate across fields with three different specialty crops identified as important to the San Joaquin Valley (tomatoes, almonds, vineyards) and with potential suitability for OFFCR. A prime goal of the field study was to provide data for parameterizing two models developed to assess nitrate, salt and water transport through the vadose zone, prior to percolating into the groundwater aquifer.However, the field study also resulted in key findings that show its value as a stand-alone study: 1) Nitrate concentrations are highest in the upper vadose zone and affected by texture. Those effects are not evident in the deeper vadose zone. 2) Vadose zone nitrate concentrations are affected by the crop grown. These results suggest an opportunity for lower legacy mass transport for grapes and higher legacy mass transport for both tomatoes and almonds.3) Variability in individual farmers’ past and present fertilizer and water management practices contributes to different legacy salt and nitrate loads in the vadose zone.Data from the field study and other related and concurrent OFFCR field efforts were used during model development. The overall modeling approach was designed to model nitrate and salt transport for lands under OFFCR operation for different crop types, vadose zone characteristics and groundwater characteristics. The defined goals of this design and modeling approach were to: 1) model nitrate and salt movement through the vadose zone and into groundwater; 2) test the model against scenarios that consider different recharge rates, cultural practices, soil types, and depths to groundwater, assessing the timing and magnitude of loading through the vadose zone and the effects on underlying groundwater; and 3) recommend management practices to mitigate potential groundwater impacts. To achieve these goals, two models were integrated to simulate nitrate and salt transport through the vadose zone to groundwater under different scenarios: a 1D Hydrus model and an analytical groundwater model (AGM).
    Description: USDA Specialty Crop Block Grants, CA. Grant Agreement SCB14028
    Description: Nitrate Leaching Risk from Specialty Crop Fields During On-Farm Managed Floodwater Recharge in the Kings Groundwater Basin [USDA Project No: PIN #26174]
    Description: Groundwater Recharge Project, 2016
    Description: On-Farm Recharge Studies, Central Valley, CA
    Keywords: Agriculture ; Chemistry ; Earth Sciences ; Engineering ; Environment ; Management ; Planning ; Pollution ; on-farm recharge ; floodmar ; groundwater ; management ; agriculture ; water quality ; vadose zone ; nitrate ; BMPs ; Kings Groundwater Basin
    Repository Name: AquaDocs
    Type: monograph
    Format: application/pdf
    Format: application/pdf
    Format: 27
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 900-903 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study concerns the determination of stagnation point and minimum pressure point film thicknesses when a vertical flat plate is withdrawn from a reservoir containing non-Newtonian liquids. Upon consideration of three types of liquids, namely, Ellis, power law, and Bingham liquids, it has been found that stagnation point or minimum pressure point film thickness is a function of two parameters, one characterizing the liquid and the other representing parallel flow film thickness. It has also been shown that in the case of power law liquids, both the stagnation point and minimum pressure point exist, while in the case of Bingham liquids, the existence of one or both the points for a given nondimensional parallel flow film thickness depends upon the value of the Bingham number. Furthermore, it has been found that there may be situations when both the points can coincide; for example, in the case of Newtonian liquids, the two points coincide if the parallel flow film thickness is \documentclass{article}\pagestyle{empty}\begin{document}$ \sqrt {2 - \sqrt 3 } $\end{document}.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 21 (1979), S. 775-785 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Equine liver alcohol dehydrogenase (EC 1.1.1.1) has been purified by a new scheme using a blue agarose gel (Blue Sepharose) as an affinity sorbent. Starting amounts of 0.6 to 10 kg liver have been processed to enzyme possessing 1.5 U/mg average specific activity, in about three to four days. Some parameters concerning adsorption of enzyme to the blue gel as well as recovery therefrom have been explored.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 541-547 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The use of swelling anisotropy as a means of determining the orientation of cellulose fibers has been critically reviewed, and it has been shown that the method should be suitable for highly oriented fibers within a certain range of orientation. The application of the method to untreated and variously treated jute fibers reveals certain structural differences with ramie, of which the following are noteworthy. Both noncrystalline and crystalline orientations of jute are influenced by treatments which can be regarded as being confined to the intercrystalline regions only and which do not affect ramie. As compared with ramie, the ultimate maximum disorientation, produced on mercerization treatment is markedly less in jute, and this holds for both the crystalline as well as the noncrystalline components of the fiber.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. 533-540 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Measurements have been made of the shrinkage in alkali and of the permanent contraction resulting from alkali treatment. The results supported by x-ray evidence following the changes in orientation and degree of mercerization show that the shrinkage of jute is subject to a similar restraint as swelling, and the shrinkage behavior of jute compared to ramie is as that of a yarn compared to that of its constituent fibers. Unlike swelling, the shrinkage of jute at dilute alkali is less than that of ramie and the corresponding region of the shrinkage curve is conspicuous by the smoothness of swelling curve, indicating that the shrinkage refers primarily to the structural framework of the fiber, whereas an extrastructural material may contribute to swelling. Although the crystallinity of jute is comparable to that of rayon, no appreciable permanent contraction occurs in the fiber treated in dilute alkali, and this points to a restraint in the structure of jute similar to that exercised by the crystallites in ramie. Whereas the resistance in ramie is completely neutralized in mercerizing alkali and the whole of the alkali shrinkage remains as permanent contraction, the restraint still operates in jute, and the permanent contraction is in deficit of the alkali shrinkage. The respective disorientations are also of the same order. Both permanent contraction and crystalline disorientation continually increase on repeated alkali treatments of jute and ramie; the additional effect found in jute is its complete mercerization after a number of treatments. The shrinkage as indexed by its maximum value is strongly correlated with the oriented state of the fiber, and the disorientation produced in jute on dilute alkali treatment is followed by a lower maximum shrinkage. Incomplete disorientation of mercerized jute shows up in positive shrinkage and its proportion is the same as that of unconverted cellulose I residue. In spite of a very high degree of orientation, the reoriented fiber shows a considerably low maximum shrinkage compared to the native. This is suggested to have been due to the formation of some junction points when the freely swollen plasticized fiber is mechanically strained.
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 3427-3437 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It was shown that the shape of the scattering pattern is not only related to the shape but also to the face-orientation of the lamellar scattering units, and an actual observation of its characteristic shape depends on the amount and dispersion of their spiral angle. The following results were obtained: (1) For observing a cross-pattern, the critical spiral angles corresponding to minimum and maximum dispersions are 7.5° and 30° respectively, whereas in an actual fiber, coir, the critical angle is about 16.75°. (2) The jute pattern changes from a uniformly narrow to a triangular shape on disorientation and reverts to the former on reorientation. The corresponding changes in ramie are from a triangular to a uniformly wide and then to a uniformly narrow shape. Both native and disoriented cottons give weak, fan-shaped scattering superimposed on a more intense elliptical pattern. The pattern given by reoriented cotton is roughly a narrow streak. Delignified jute gives a somewhat shaving-brush-shaped pattern which changes to a uniformly wide streak on alkali treatment. (3) The extent of scattering decreases on swelling and increases on stretching in jute, ramie, and cotton, but decreases in stretched coir.
    Additional Material: 25 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 3439-3450 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It was shown that the realization of a straight log I-h2 curve may be a coincidence depending on the relative influence of heterogeneity of distribution and non-independent scattering, and a concave log I-h2 curve can represent a nonhomogeneous system amenable to Shull and Roess's method of analysis. The results indicate: (1) The I-h curve for a jute holo-cellulose film has a maximum, and that for a ramie film an inflexion point, each superimposed on a background of gradually declining intensity, and in either case the singularity is accentuated and shifted to a region of larger angle on alkali-treatment. (2) The log I-h2 plots for untreated, alkali-treated and stretched jute fibers give straight sections in the low-angle, and convex, concave, and straight sections, respectively, in the high-angle region. An interesting feature of the results for ramie is the realization of a straight logarithmic curve on mercerization. The curves for alkali-treated and stretched Fortisan fibers have also each of them two discernible linear parts, indicative of two groups of scatterers. (3) An evaluation of the log I-log h2 curves by Shull and Roess's method leads to figures for the diameters of the scattering elements in ramie comparable to those estimated from the corresponding log I-h2 plots.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 9 (1995), S. 91-92 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A sample of poly(methyl methacrylate) (PMMA), of which the molecular weight was known from light-scattering measurements, was subjected to gel-perrneation-chromatographic analysis, and the resulting Weight versus log molecular weight (MW) plot was converted by suitable computation to a Number versus linear MW plot. This could then be compared directly with the matrix-assisted laser desorption ionization MW distribution results obtained for the same sample. The MW distributions obtained by the two methods were significantly different. Two explanations for the discrepancy are offered.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Electrophoresis 5 (1984), S. 133-138 
    ISSN: 0173-0835
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Two polyacrylamide gel electrophoretic systems for the separation of small peptides are described. In both systems the samples are concentrated by a buffer discontinuity, and the peptides separated according to size and charge in 40-50 % polyacrylamide resolving gels. The acidic gel has an operative pH between 3.0 and 3.1 while the alkaline gel has an operative pH between 9.1 and 9.2. The lower limit of resolution is about 100 daltons for a peptide with one positive charge in the acidic system. The radioactive peptides are detected by autoradiography. Peptides with a free amino group can be fixed in these gels with formaldehyde, so that fluorographic procedures can also be used for increased sensitivity. These techniques enable precise comparison of non-derivatized peptides from complete protein fingerprints and offer a simple one-dimensional analytical method for protein comparison, as well as a general method for separating and analyzing small peptides.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 25 (1980), S. 1737-1744 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of heat treatment in the presence and absence of a nonionic surfactant (Triton X-100) on selected properties of polyester fabric was studied over the temperature range 180-220°C. Although significant heat-induced area shrinkage was evident (4.9-9.5%) in the treated polyester fabrics, stiffness, wrinkle recovery, tensile properties, moisture regain, and density of the fabrics showed only slight changes. The moisture-related properties of surfactant/heat-treated polyester were greatly improved compared to untreated control polyester or polyester subjected to heat treatment alone. Oligomer formation on the surface of surfactant-treated polyester was altered as a result of the presence of surfactant on heating compared to polyester heated alone at 180-220°C. Polyester heat treated in the presence and absence of surfactant showed increased dye uptake and more depth of color with 1,4-substituted anthraquinone dyes than untreated polyester, and these effects increased with increasing treatment temperature.
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