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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Il nuovo cimento della Società Italiana di Fisica 16 (1994), S. 1401-1410 
    ISSN: 0392-6737
    Keywords: Mechanical properties of liquids ; Conference proceedings
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Summary Both linear and non-linear viscoelasticity experiments have been performed in semi-dilute micellar aqueous solutions of ethanediyl-α,ω-bis (dodecylmethylammonium bromide) as a function of solution chloride (NaCl) concentration. The results suggest that both linear and non-linear properties are affected by the electrostatic interactions. In particular, the plateau modulusG′∞ and the ratioσ m/G′∞, whereσ m represents the plateau value in a stress-shear rate experiment, are enhanced as the electrostatic interactions are screened by addition of salt. The zero-shear viscosity is lowered upon addition of NaCl, due likely to an exchange of the Cl− ions with the Br− counterions.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 10 (1971), S. 2635-2638 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 12 (1973), S. 79-87 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ultrasonic absorption measurements were carried out on solutions of polybenzyl-L-aspartate (PBLA) in chloroform-dichloroacetic acid (DCA) and in 1,2-dichloroethane (DCE)-DCA, in the range 3.9-155 MHZ. The helix-coil transition of PBLA produces an increase of absorption which is larger in CHCl3-DCA than in DCE-DCA solutions. The influence of the solvent on the excess ultrasonic absorption suggests that solvation processes may be involved in these changes of absorption. The plots of the absorption vs. the volume fraction of DCA do not show any absorption maximum. This indicates that the ultrasonic absorption is not sensitive to the helix-coil equilibrium of PBLA in the frequency range investigated. A maximum value of 109 S-1 has been obtained for the rate constant of growth of a helix region.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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