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  • Chemistry  (10)
  • Aegilops squarrosa  (2)
  • 1
    ISSN: 1573-5060
    Schlagwort(e): Triticum turgidum ssp. dicoccoides ; wild emmer wheat ; Aegilops squarrosa ; interspecific hybridisation ; synthetic hexaploid wheat ; chromosome doubling ; embryo rescue ; meiosis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Summary Triticum turgidum ssp. dicoccoides (wild emmer wheat, AABB, 2n=28) and Aegilops squarrosa (goat grass, DD, 2n=14) comprise a rich reservoir of valuable genetic material, which could be useful for the breeding of common wheat (T. aestivum, AABBDD, 2n=42). Many accessions of both wild species, most of them selected for resistance to stripe rust, were used to make amphiploids. Two strategies were applied: (1) the production of autopolyploid cytotypes of the wild species, followed by hybridisation, and (2) the production of allotriploid interspecific hybrids, followed by doubling of the number of chromosomes. The first route was unsuccessful because of failure of the crosses between the autopolyploid cytotypes, possibly due to incongruity between the two species and to reduced fertility in the autopolyploid cytotypes. The second route yielded the desired synthetic hexaploids. However, the rate of success of the crosses was low and there were great differences between years, and within years between crosses. Embryo rescue was applied to obtain the primary hybrids (2n=21), which were highly sterile and had on average 0.3 bivalents and 20.4 univalents per pollen mother cell. Various abnormalities were recorded. Doubling of the number of chromosomes sometimes occurred spontaneously or was brought about by colchicine treatment. The large scale of the interspecific hybridisation programme ensured that one-third of the female and one-sixth of the male accessions were represented in the synthetic hexaploids.
    Materialart: Digitale Medien
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  • 2
    ISSN: 1573-5060
    Schlagwort(e): Triticum turgidum ssp. dicoccoides ; wild emmer wheat ; Aegilops squarrosa ; synthethic hexaploid wheat ; breeding common wheat ; Triticum aestivum ; meiosis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Summary Novel amphiploids or synthetic hexaploid wheats, derived from eleven accessions of Triticum turgidum ssp. dicoccoides (wild emmer wheat, AABB, 2n=28) and eight accessions of Aegilops squarrosa (goat grass, DD, 2n=14) were studied. Most amphiploids were normal, vigorous and fertile. Among amphiploids a wide variation for morphological characteristics was observed. The glumes were found very tenacious and the rachis tough, or nearly so. First metaphase of meiosis proved to be quite regular; however, some aneuploid offspring occurred in successive generations. In F1 hybrids between T. aestivum (common wheat, AABBDD, 2n=42) ‘Chinese Spring’ and the synthetic hexaploids the rate of chromosome association was lower than in both parents, and significant differences were observed between amphiploids. Multivalents occurred in very low frequencies in these F1 hybrids. The rate of chromosome association in a hybrid between two synthetic hexaploids was found to be very low. The results are discussed in terms of genetic interactions and structural differences between the genomes of the respective species.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 39 (1926), S. 65-67 
    ISSN: 0044-8249
    Schlagwort(e): Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 29 (1991), S. S118 
    ISSN: 0749-1581
    Schlagwort(e): 103Rh NMR ; 31P NMR ; Inverse 2D NMR ; Square planar ; Cation ; Diphosphine ; Paramagnetic shift ; Chemical shift correlation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: A series of new and known Rh(I) complexes [Rh(R2P(CH2)nPR2)2]Y and [Rh(diene)(R2P(CH2)nPR2)]Y (R = Me, Et, Ph, C6F5, C6H4CF3; Y = Cl, ClO4, PF4, BF4, OSO2CF3; diene = norbornadiene, cyclooctadiene) were prepared and their 103Rh NMR spectra were recorded on a 100-MHz spectrometer by using inverse two-dimensional 31P, 103Rh{1H} NMR. This technique provides quick access to 103Rh NMR data (2-8 h for ca. 0.1 M samples) when dealing with Rh-phosphine complexes. The 103Rh NMR data are discussed. All δ(103Rh) of the cationic Rh(I) complexes appear at the lower frequency end of the Rh(I) range, i.e. between -1350 and + 200 ppm, which is in agreement with the fact that the Rh shift is determined by σp and with a large ΔE in square-planar d8 complexes. The relative change in ΔE between complexes is not large and the changes in paramagnetic shift for these complexes are essentially determined by their relative σ-donor capacities. δ(103Rh) shows an inverse correlation with δ(31P), which was rationalized by invoking the chelate ring size containing the Rh centre and the bidentate phosphine ligands.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 326 (1964), S. 280-287 
    ISSN: 0044-2313
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: The preparations of certain amino dialkyl arsines (R2As—N(C2H5)2 and R2As—NC5H10 with R = C2H5, C3H7 or C4H9) are discribed. These compounds react with H2O, CH3J or HCl by cleaving the As—N bond, forming R2AsCl in the last case. The dialkyl chloro arsines are reduced by LiAlH4 to the corresponding arsines.
    Notizen: Diäthylamino- und Piperidino-dichlorarsine reagieren mit aliphatischen Grignard-Verbindungen im Molverhältnis 1:2 unter Bildung der Amino-dialkylarsine R2As—N(C2H5)2 und R2As—NC5H10 (R = C2H5, C2H5, C3H7 oder C4H9). Die Amino-dialkylarsine sind äußerst hydrolyseempfindlich, wobei eine quantitative Spaltung der As—N-Bindung stattfindet. Eine Spaltung dieser Bindung resultiert gleichfalls mit HCl-Gas. Es werden hierbei Amin-hydrochloride und aliphatische Chlorarsine R2AsCl gebildet. Letztere lassen sich mit LiAlH4 zu den entsprechenden Dialkylarsinen R2AsH reduzieren. In den Amino-dialkylarsinen fungiert das Stickstoffatom als basisches Zentrum, wie aus der Ammoniumsalzbildung mittels CH3J zu folgern ist.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 330 (1964), S. 317-323 
    ISSN: 0044-2313
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Tertiary aromaric and aliphatic-aromatic arsines react with potassium in dioxan solution by decomposition forming the alkali arsides KAsR2 (R = C10H7-, p-CH3—C6H4—) and KAsRR′ (R = C6H5-; R = C2H5-, C6H11-). Cleaving only occurs with arsines containing two aromatic groups, but dialkyl-aryl arsines and trialkyl arsines are indifferent. Hydrolysis of KAsR2 and KAsRR′ yields the corresponding see, arsines and reaction with hydrocarbon halides gives the corresponding tert. arsines.
    Notizen: Tertiäre aromatische sowie aliphatisch-aromatische Arsine reagieren mit Kalium in Dioxan unter Abspaltung eines Restes und Bildung der Alkali-arside des Typs KAsR2 (R = C10H7- und p-CH3—C6H4-) bzw. KAsRR′ (R = C6H5; R′ = C2H5; R′ = C2H5-, und C6H11-). Für eine positive Spaltung ist die Anwesenheit zweier aromatischer Reste Voraussetzung. Dialkyl-arylarsine und Trialkyl-arsine verhalten sich gegenüber Kalium in Dioxan indifferent. Nach Hydrolyse der Alkali-arside lassen sich die betreffenden sekundären Arsine gewinnen. Mit Alkylhalogenid liefern die Alkaliarside die entsprechenden tertiären Arsine.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 38 (1905), S. 2766-2769 
    ISSN: 0365-9496
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 39 (1906), S. 392-397 
    ISSN: 0365-9496
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 39 (1906), S. 2346-2356 
    ISSN: 0365-9496
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 11 (1878), S. 822-826 
    ISSN: 0365-9496
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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